Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials

Abstract: A new method of supramolecular polymerization at the water–oil interface is developed. As a demonstration, an oil‐soluble supramonomer containing two thiol end groups linked by two ureidopyrimidinone units and a water‐soluble monomer bearing two maleimide end groups are employed. Supramolecular interfacial polymerization can be implemented by a thiol–maleimide click reaction at the water–chloroform interface to obtain supramolecular polymeric films. The glass transition temperature of such supramolecular polymers can be well‐tuned by simply changing the polymerization time and temperature. It is highly anticipated that this work will provide a facile and general approach to realize control over supramolecular polymerization by transferring the preparation of supramolecular polymers from solutions to water–oil interfaces and construct supramolecular materials with well‐defined properties.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials ; volume:56 ; number:26 ; year:2017 ; pages:7639-7643 ; extent:5
Angewandte Chemie / International edition. International edition ; 56, Heft 26 (2017), 7639-7643 (gesamt 5)

Creator
Qin, Bo
Zhang, Shuai
Song, Qiao
Huang, Zehuan
Xu, Jiang‐Fei
Zhang, Xi

DOI
10.1002/anie.201703572
URN
urn:nbn:de:101:1-2022091705485250018636
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:20 AM CEST

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Associated

  • Qin, Bo
  • Zhang, Shuai
  • Song, Qiao
  • Huang, Zehuan
  • Xu, Jiang‐Fei
  • Zhang, Xi

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