Electrochemical Palladium‐Catalyzed Oxidative Carbonylation‐Cyclization of Enallenols
Abstract: Herein, we report an electrochemical oxidative palladium‐catalyzed carbonylation‐carbocyclization of enallenols to afford γ‐lactones and spirolactones, which proceeds with excellent chemoselectivity. Interestingly, electrocatalysis was found to have an accelerating effect on the rate of the tandem process, leading to a more efficient reaction than that under chemical redox conditions.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Electrochemical Palladium‐Catalyzed Oxidative Carbonylation‐Cyclization of Enallenols ; day:04 ; month:11 ; year:2022 ; extent:1
Angewandte Chemie / International edition. International edition ; (04.11.2022) (gesamt 1)
- Creator
- DOI
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10.1002/anie.202212131
- URN
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urn:nbn:de:101:1-2022110514101907041482
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:33 AM CEST
Data provider
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Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Zhang, Jianwei
- Das, Biswanath
- Verho, Oscar
- Bäckvall, Jan-E.
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Palladium-catalyzed carbonylation reactions of aryl halides
Palladium-catalyzed carbonylation of unsaturated carbon-carbon bonds
Palladium‐Catalyzed Carbonylation in the Synthesis of N‐Ynonylsulfoximines
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