Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron (IV) Oxo Complexes in the Gas Phase

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Abstract: Closely structurally related triplet and quintet iron (IV) oxo complexes with a tetradentate aminopyridine ligand were generated in the gas phase, spectroscopically characterized, and their reactivities in hydrogen‐transfer and oxygen‐transfer reactions were compared. The spin states were unambiguously assigned based on helium tagging infrared photodissociation (IRPD) spectra of the mass‐selected iron complexes. It is shown that the stretching vibrations of the nitrate counterion can be used as a spectral marker of the central iron spin state.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron (IV) Oxo Complexes in the Gas Phase ; volume:128 ; number:11 ; year:2016 ; pages:3701-3705 ; extent:5
Angewandte Chemie ; 128, Heft 11 (2016), 3701-3705 (gesamt 5)

Creator: Andris, Erik
Jašík, Juraj
Gómez, Laura
Costas, Miquel
Roithova, Jana

DOI: 10.1002/ange.201511374

URN: urn:nbn:de:101:1-2022103104441523672440

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:22 AM CEST

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Andris, Erik
Jašík, Juraj
Gómez, Laura
Costas, Miquel
Roithova, Jana

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Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron (IV) Oxo Complexes in the Gas Phase

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Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron (IV) Oxo Complexes in the Gas Phase

Reactivity Differences of Trigonal Pyramidal Nonheme Iron (IV)‐Oxo and Iron (III)‐Oxo Complexes: Experiment and Theory

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Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron (IV) Oxo Complexes in the Gas Phase

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Other Objects (12)

Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron (IV) Oxo Complexes in the Gas Phase

Reactivity Differences of Trigonal Pyramidal Nonheme Iron (IV)‐Oxo and Iron (III)‐Oxo Complexes: Experiment and Theory

M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt (III)‐Oxyl and Cobalt (III)‐Oxo Complexes

M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt (III)‐Oxyl and Cobalt (III)‐Oxo Complexes

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Reactivity Differences of Trigonal Pyramidal Nonheme Iron (IV)‐Oxo and Iron (III)‐Oxo Complexes: Experiment and Theory

M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt (III)‐Oxyl and Cobalt (III)‐Oxo Complexes

M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt (III)‐Oxyl and Cobalt (III)‐Oxo Complexes

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Towards rhodium and iridium oxo complexes

Synthesis, spectroscopic characterization and reactivity of the high-valent metal-oxo/imido cores of the late transition metals

Experimental study on spectroscopic signatures of spin-triplet superconductivity

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Spectroscopic investigations of the lowest triplet state of s-tetrazines

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M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt (III)‐Oxyl and Cobalt (III)‐Oxo Complexes

Matrix Isolation and IR Spectroscopic Study on Late-Transition Fluorides, Metal Oxo Complexes and Actinide Halides

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Experimental study on spectroscopic signatures of spin-triplet superconductivity

Tuning the H‐Atom Transfer Reactivity of Iron(IV)‐Oxo Complexes as Probed by Infrared Photodissociation Spectroscopy

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Spectroscopic investigations of the lowest triplet state of s-tetrazines

Reactivity of P4 butterfly complexes

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