Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron (IV) Oxo Complexes in the Gas Phase
Abstract: Closely structurally related triplet and quintet iron (IV) oxo complexes with a tetradentate aminopyridine ligand were generated in the gas phase, spectroscopically characterized, and their reactivities in hydrogen‐transfer and oxygen‐transfer reactions were compared. The spin states were unambiguously assigned based on helium tagging infrared photodissociation (IRPD) spectra of the mass‐selected iron complexes. It is shown that the stretching vibrations of the nitrate counterion can be used as a spectral marker of the central iron spin state.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron (IV) Oxo Complexes in the Gas Phase ; volume:55 ; number:11 ; year:2016 ; pages:3637-3641 ; extent:5
Angewandte Chemie / International edition. International edition ; 55, Heft 11 (2016), 3637-3641 (gesamt 5)
- Urheber
- DOI
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10.1002/anie.201511374
- URN
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urn:nbn:de:101:1-2022110106113026988718
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:25 MESZ
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Beteiligte
- Andris, Erik
- Jašík, Juraj
- Gómez, Laura
- Costas, Miquel
- Roithova, Jana
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