Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages
Abstract: Heteroleptic metal‐organic cages, formed through integrative self‐assembly of ligand mixtures, are highly attractive as reduced symmetry supramolecular hosts. Ensuring high‐fidelity, non‐statistical self‐assembly, however, presents a significant challenge in molecular engineering due to the inherent difficulty in predicting thermodynamic energy landscapes. In this work, two conceptual strategies are described that circumvent this issue, using ligand design strategies to access structurally sophisticated metal‐organic hosts. Using these approaches, it was possible to realise cavity environments described by two inequivalent, unsymmetrical ligand frameworks, representing a significant step forward in the construction of highly anisotropic confined spaces.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages ; day:30 ; month:09 ; year:2022 ; extent:1
Angewandte Chemie ; (30.09.2022) (gesamt 1)
- Urheber
-
Lewis, James E. M.
- DOI
-
10.1002/ange.202212392
- URN
-
urn:nbn:de:101:1-2022100115182776922228
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:21 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Lewis, James E. M.
Ähnliche Objekte (12)
Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages
Mechanoresponsive metal-organic cage-crosslinked polymer hydrogels
Mechanoresponsive Metal‐Organic Cage‐Crosslinked Polymer Hydrogels
Nanogels with Metal‐Organic Cages as Functional Crosslinks
Thermally-induced atropisomerism promotes metal-organic cage construction
Nanogels with Metal‐Organic Cages as Functional Crosslinks
Reversible switching of arylazopyrazole within a metal–organic cage
Hydrogen Isotope Separation Using a Metal–Organic Cage Built from Macrocycles
Protection and Transformation of Natural Products within Aqueous Metal‐Organic Cages
Hydrogen Isotope Separation Using a Metal–Organic Cage Built from Macrocycles
Fabrication of Self‐Expanding Metal–Organic Cages Using a Ring‐Openable Ligand
Fabrication of Self‐Expanding Metal–Organic Cages Using a Ring‐Openable Ligand
Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages
Mechanoresponsive metal-organic cage-crosslinked polymer hydrogels
Mechanoresponsive Metal‐Organic Cage‐Crosslinked Polymer Hydrogels
Nanogels with Metal‐Organic Cages as Functional Crosslinks
Thermally-induced atropisomerism promotes metal-organic cage construction
Nanogels with Metal‐Organic Cages as Functional Crosslinks
Reversible switching of arylazopyrazole within a metal–organic cage
Hydrogen Isotope Separation Using a Metal–Organic Cage Built from Macrocycles
Protection and Transformation of Natural Products within Aqueous Metal‐Organic Cages
Hydrogen Isotope Separation Using a Metal–Organic Cage Built from Macrocycles
Fabrication of Self‐Expanding Metal–Organic Cages Using a Ring‐Openable Ligand
Fabrication of Self‐Expanding Metal–Organic Cages Using a Ring‐Openable Ligand
Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages
Mechanoresponsive metal-organic cage-crosslinked polymer hydrogels
Mechanoresponsive Metal‐Organic Cage‐Crosslinked Polymer Hydrogels
Nanogels with Metal‐Organic Cages as Functional Crosslinks
Thermally-induced atropisomerism promotes metal-organic cage construction
Nanogels with Metal‐Organic Cages as Functional Crosslinks
Reversible switching of arylazopyrazole within a metal–organic cage
Hydrogen Isotope Separation Using a Metal–Organic Cage Built from Macrocycles
Protection and Transformation of Natural Products within Aqueous Metal‐Organic Cages
Hydrogen Isotope Separation Using a Metal–Organic Cage Built from Macrocycles
Fabrication of Self‐Expanding Metal–Organic Cages Using a Ring‐Openable Ligand