Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages

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Abstract: Heteroleptic metal‐organic cages, formed through integrative self‐assembly of ligand mixtures, are highly attractive as reduced symmetry supramolecular hosts. Ensuring high‐fidelity, non‐statistical self‐assembly, however, presents a significant challenge in molecular engineering due to the inherent difficulty in predicting thermodynamic energy landscapes. In this work, two conceptual strategies are described that circumvent this issue, using ligand design strategies to access structurally sophisticated metal‐organic hosts. Using these approaches, it was possible to realise cavity environments described by two inequivalent, unsymmetrical ligand frameworks, representing a significant step forward in the construction of highly anisotropic confined spaces.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages ; day:30 ; month:09 ; year:2022 ; extent:1
Angewandte Chemie ; (30.09.2022) (gesamt 1)

Creator: Lewis, James E. M.

DOI: 10.1002/ange.202212392

URN: urn:nbn:de:101:1-2022100115182776922228

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:21 AM CEST

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Lewis, James E. M.

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