α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping
Abstract: A general and straightforward procedure for the lithiation trapping of cyclic sulfides such as tetrahydrothiophene, tetrahydrothiopyran and a thiomorpholine is described. Trapping with a wide range of electrophiles is demonstrated, leading to more than 50 diverse α‐substituted saturated sulfur heterocycles. The methodology provides access to a range of α‐substituted cyclic sulfides that are not easily synthesised by the currently available methods.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping ; day:07 ; month:12 ; year:2023 ; extent:7
Angewandte Chemie ; (07.12.2023) (gesamt 7)
- Urheber
-
Seling, Nico
Atobe, Masakazu
Kasten, Kevin
Firth, James D.
Karadakov, Peter B.
Goldberg, Frederick W.
O'Brien, Peter
- DOI
-
10.1002/ange.202314423
- URN
-
urn:nbn:de:101:1-2023120814471398638023
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:29 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Seling, Nico
- Atobe, Masakazu
- Kasten, Kevin
- Firth, James D.
- Karadakov, Peter B.
- Goldberg, Frederick W.
- O'Brien, Peter
Ähnliche Objekte (12)
α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping
Organic functionalisation and post-functionalisation of polynuclear vanadium compounds
One-pot functionalisation of N-substituted tetrahydroisoquinolines by photooxidation and tunable organometallic trapping of iminium intermediates
Synthesis of novel sulfide-based cyclic peptidomimetic analogues to solonamides
Functionalisation of silica–carbonate biomorphs
Functionalisation of Chromane by Deprotonative Metallation
Cationic Functionalisation by Phosphenium Ion Insertion
Catalyst-controlled functionalisation and isomerisation of Alkenes
Bridge Functionalisation of Bicyclo[1.1.1]pentane Derivatives
Advances in the functionalisation of polyphosphorus ligands
Bridge Functionalisation of Bicyclo[1.1.1]pentane Derivatives
Functionalisation of 2D-Semiconductors with Organic Molecules
α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping
Organic functionalisation and post-functionalisation of polynuclear vanadium compounds
One-pot functionalisation of N-substituted tetrahydroisoquinolines by photooxidation and tunable organometallic trapping of iminium intermediates
Synthesis of novel sulfide-based cyclic peptidomimetic analogues to solonamides
Functionalisation of silica–carbonate biomorphs
Functionalisation of Chromane by Deprotonative Metallation
Cationic Functionalisation by Phosphenium Ion Insertion
Catalyst-controlled functionalisation and isomerisation of Alkenes
Bridge Functionalisation of Bicyclo[1.1.1]pentane Derivatives
Advances in the functionalisation of polyphosphorus ligands
Bridge Functionalisation of Bicyclo[1.1.1]pentane Derivatives
Functionalisation of 2D-Semiconductors with Organic Molecules
α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping
Organic functionalisation and post-functionalisation of polynuclear vanadium compounds
One-pot functionalisation of N-substituted tetrahydroisoquinolines by photooxidation and tunable organometallic trapping of iminium intermediates
Synthesis of novel sulfide-based cyclic peptidomimetic analogues to solonamides
Functionalisation of silica–carbonate biomorphs
Functionalisation of Chromane by Deprotonative Metallation
Cationic Functionalisation by Phosphenium Ion Insertion
Catalyst-controlled functionalisation and isomerisation of Alkenes
Bridge Functionalisation of Bicyclo[1.1.1]pentane Derivatives
Advances in the functionalisation of polyphosphorus ligands
Bridge Functionalisation of Bicyclo[1.1.1]pentane Derivatives