α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping

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Abstract: A general and straightforward procedure for the lithiation trapping of cyclic sulfides such as tetrahydrothiophene, tetrahydrothiopyran and a thiomorpholine is described. Trapping with a wide range of electrophiles is demonstrated, leading to more than 50 diverse α‐substituted saturated sulfur heterocycles. The methodology provides access to a range of α‐substituted cyclic sulfides that are not easily synthesised by the currently available methods.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping ; day:07 ; month:12 ; year:2023 ; extent:7
Angewandte Chemie ; (07.12.2023) (gesamt 7)

Creator: Seling, Nico
Atobe, Masakazu
Kasten, Kevin
Firth, James D.
Karadakov, Peter B.
Goldberg, Frederick W.
O'Brien, Peter

DOI: 10.1002/ange.202314423

URN: urn:nbn:de:101:1-2023120814471398638023

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:29 AM CEST

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Seling, Nico
Atobe, Masakazu
Kasten, Kevin
Firth, James D.
Karadakov, Peter B.
Goldberg, Frederick W.
O'Brien, Peter

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Organic functionalisation and post-functionalisation of polynuclear vanadium compounds

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Synthesis of novel sulfide-based cyclic peptidomimetic analogues to solonamides

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Organic functionalisation and post-functionalisation of polynuclear vanadium compounds

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Synthesis of novel sulfide-based cyclic peptidomimetic analogues to solonamides

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α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping

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Other Objects (12)

α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping

Organic functionalisation and post-functionalisation of polynuclear vanadium compounds

One-pot functionalisation of N-substituted tetrahydroisoquinolines by photooxidation and tunable organometallic trapping of iminium intermediates

Synthesis of novel sulfide-based cyclic peptidomimetic analogues to solonamides

Functionalisation of silica–carbonate biomorphs

Functionalisation of Chromane by Deprotonative Metallation

Cationic Functionalisation by Phosphenium Ion Insertion

Catalyst-controlled functionalisation and isomerisation of Alkenes

Bridge Functionalisation of Bicyclo[1.1.1]pentane Derivatives

Advances in the functionalisation of polyphosphorus ligands

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Functionalisation of 2D-Semiconductors with Organic Molecules

α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping

Organic functionalisation and post-functionalisation of polynuclear vanadium compounds

One-pot functionalisation of N-substituted tetrahydroisoquinolines by photooxidation and tunable organometallic trapping of iminium intermediates

Synthesis of novel sulfide-based cyclic peptidomimetic analogues to solonamides

Functionalisation of silica–carbonate biomorphs

Functionalisation of Chromane by Deprotonative Metallation

Cationic Functionalisation by Phosphenium Ion Insertion

Catalyst-controlled functionalisation and isomerisation of Alkenes

Bridge Functionalisation of Bicyclo[1.1.1]pentane Derivatives

Advances in the functionalisation of polyphosphorus ligands

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Functionalisation of 2D-Semiconductors with Organic Molecules

α‐Functionalisation of Cyclic Sulfides Enabled by Lithiation Trapping

Organic functionalisation and post-functionalisation of polynuclear vanadium compounds

One-pot functionalisation of N-substituted tetrahydroisoquinolines by photooxidation and tunable organometallic trapping of iminium intermediates

Synthesis of novel sulfide-based cyclic peptidomimetic analogues to solonamides

Functionalisation of silica–carbonate biomorphs

Functionalisation of Chromane by Deprotonative Metallation

Cationic Functionalisation by Phosphenium Ion Insertion

Catalyst-controlled functionalisation and isomerisation of Alkenes

Bridge Functionalisation of Bicyclo[1.1.1]pentane Derivatives

Advances in the functionalisation of polyphosphorus ligands

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Functionalisation of 2D-Semiconductors with Organic Molecules

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