Synthesis and dark state EPR properties of PDI‐trityl dyads and triads
Abstract: Covalently-linked chromophore-radical systems with their unique optical and magnetic properties are useful for applications in, e. g., quantum information science. To expand the catalog of molecular systems, we synthesized and characterized six novel chromophore–radical and radical-chromophore-radical systems employing derivatives of perylene diimide (PDI) as the chromophore and trityl as the radical. The EPR properties of these compounds were evaluated in solution at cryogenic and room temperatures. In addition, the electron spin-spin coupling in the two bistrityl systems was investigated using DQC measurements. The presented results serve as a basis for further spectroscopic investigations under photoexcitation of the PDI core
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Anmerkungen
-
Chemistry - a European journal. - 30, 12 (2024) , e202303635, ISSN: 1521-3765
- Ereignis
-
Veröffentlichung
- (wo)
-
Freiburg
- (wer)
-
Universität
- (wann)
-
2024
- Urheber
-
Kopp, Kevin
Westhofen, Lars
Hett, Tobias
Schwering‐Sohnrey, Merlin Felix
Mayländer, Maximilian
Richert, Sabine
Schiemann, Olav
- DOI
-
10.1002/chem.202303635
- URN
-
urn:nbn:de:bsz:25-freidok-2466038
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
25.03.2025, 13:48 MEZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Kopp, Kevin
- Westhofen, Lars
- Hett, Tobias
- Schwering‐Sohnrey, Merlin Felix
- Mayländer, Maximilian
- Richert, Sabine
- Schiemann, Olav
- Universität
Entstanden
- 2024
Ähnliche Objekte (12)
Tetrabromidocuprates(II)-Synthesis, Structure and EPR
Tetrabromidocuprates(II)—synthesis, structure and EPR
Synthesis and Characterization of novel Porphyrin-Fullerene-Dyads and Cyclomalonate-linked Trisfullerene
Synthesis, Photophysics and Photocatalysis of [FeFe] Complex Containing Dyads and Bimolecular Systems
Synthesis, EPR characterization and chitosan labelling of triarylmethyl radicals
Synthesis and Characterization of Amphiphilic Porphyrin-Perylene Dyads: Towards Optoelectronic Membranes in Water
Novel NMR and EPR techniques
ENDOR and EPR of metalloproteins
Electron transfer and spin chemistry in iridium-dipyrrin dyads and triads
Electron Transfer and Spin Chemistry in Iridium-Dipyrrin Dyads and Triads
Phthalocyanine-fullerene dyads and DNA interstrand cross-linking on surface
Photoinduced electron transfer in dyads and triads with d6 metal complexes and anthraquinone
Tetrabromidocuprates(II)-Synthesis, Structure and EPR
Tetrabromidocuprates(II)—synthesis, structure and EPR
Synthesis and Characterization of novel Porphyrin-Fullerene-Dyads and Cyclomalonate-linked Trisfullerene
Synthesis, Photophysics and Photocatalysis of [FeFe] Complex Containing Dyads and Bimolecular Systems
Synthesis, EPR characterization and chitosan labelling of triarylmethyl radicals
Synthesis and Characterization of Amphiphilic Porphyrin-Perylene Dyads: Towards Optoelectronic Membranes in Water
Novel NMR and EPR techniques
ENDOR and EPR of metalloproteins
Electron transfer and spin chemistry in iridium-dipyrrin dyads and triads
Electron Transfer and Spin Chemistry in Iridium-Dipyrrin Dyads and Triads
Phthalocyanine-fullerene dyads and DNA interstrand cross-linking on surface
Photoinduced electron transfer in dyads and triads with d6 metal complexes and anthraquinone
Tetrabromidocuprates(II)-Synthesis, Structure and EPR
Tetrabromidocuprates(II)—synthesis, structure and EPR
Synthesis and Characterization of novel Porphyrin-Fullerene-Dyads and Cyclomalonate-linked Trisfullerene
Synthesis, Photophysics and Photocatalysis of [FeFe] Complex Containing Dyads and Bimolecular Systems
Synthesis, EPR characterization and chitosan labelling of triarylmethyl radicals
Synthesis and Characterization of Amphiphilic Porphyrin-Perylene Dyads: Towards Optoelectronic Membranes in Water
Novel NMR and EPR techniques
ENDOR and EPR of metalloproteins
Electron transfer and spin chemistry in iridium-dipyrrin dyads and triads
Electron Transfer and Spin Chemistry in Iridium-Dipyrrin Dyads and Triads
Phthalocyanine-fullerene dyads and DNA interstrand cross-linking on surface