When diazo compounds meet with organoboron compounds
Abstract: Transition-metal free reactions of diazo compounds with organoboron compounds provide some unique approaches for the formation of C–C, C–B and C–Si bonds. With N-tosylhydrazones as the precursors for non-stabilized diazo compound, this type of reaction becomes practically useful in organic synthesis. Transition-metal-free synthetic methodologies for borylation, gem-diborylation, gem-silylborylation arylation, 2,2,2-trifluoroethylation and gem-difluorovinylation have been successfully developed.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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When diazo compounds meet with organoboron compounds ; volume:90 ; number:4 ; year:2018 ; pages:617-623 ; extent:7
Pure and applied chemistry ; 90, Heft 4 (2018), 617-623 (gesamt 7)
- Creator
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Wang, Jianbo
- DOI
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10.1515/pac-2017-0713
- URN
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urn:nbn:de:101:1-2024022313150051804761
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 11:03 AM CEST
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Associated
- Wang, Jianbo
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