Identification of a spin-coupled Mo(III) in the nitrogenase iron-molybdenum cofactor
Abstract: Nitrogenase is the enzyme responsible for the catalytic reduction of dinitrogen (N2) to ammonia. In contrast to the industrial Haber–Bosch process that reacts N2 and H2 at high temperature and pressure, the biological reduction proceeds at ambient temperature and pressure using a complex multicomponent protein system, which utilizes eight electrons, eight protons and 16 MgATP molecules.1,2 Unraveling the structural and mechanistic details of how nature activates the strong bond of dinitrogen is of fundamental importance and this knowledge could aid in the design of better catalysts
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Anmerkungen
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Chemical science. 5, 8 (2014), 3096-3103, DOI 10.1039/c4sc00337c, issn: 2041-6539
- Schlagwort
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Nitrogenase
Haber-Bosch-Verfahren
Katalyse
Anorganische Chemie
- Ereignis
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Veröffentlichung
- (wo)
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Freiburg
- (wer)
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Universität
- (wann)
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2018
- Urheber
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Bjornsson, Ragnar
Lima, Frederico A.
Spatzal, Thomas
Weyhermüller, Thomas
Glatzel, Pieter
Bill, Eckhard
Einsle, Oliver
Neese, Frank
DeBeer, Serena
- Beteiligte Personen und Organisationen
- DOI
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10.1039/c4sc00337c
- URN
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urn:nbn:de:bsz:25-freidok-150634
- Rechteinformation
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Kein Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 14.08.2025, 11:02 MESZ
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Beteiligte
- Bjornsson, Ragnar
- Lima, Frederico A.
- Spatzal, Thomas
- Weyhermüller, Thomas
- Glatzel, Pieter
- Bill, Eckhard
- Einsle, Oliver
- Neese, Frank
- DeBeer, Serena
- Albert-Ludwigs-Universität Freiburg. Institut für Biochemie
- Albert-Ludwigs-Universität Freiburg
- Universität
Entstanden
- 2018
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