Adaptable Ultraviolet Reflecting Polymeric Multilayer Coatings of High Refractive Index Contrast

A synthetic route is demonstrated to build purely polymeric nanostructured multilayer coatings, adaptable to arbitrary surfaces, and capable of efficiently blocking by reflection a targeted and tunable ultraviolet (UV) range. Reflection properties are determined by optical interference between UV light beams reflected at the interfaces between polystyrene layers of different porosity and hence refractive index. As no dopant absorber intervenes in the shielding effect, polymer degradation effects are prevented. Alternated porosity results from the modulation of photochemical effects at the few tens of nanometers length scale, combined with the collective osmotic shock induced during the processing of the precursor diblock copolymer film. Experimental evidence of the application of this method to coat rough surfaces with smooth and conformal UV protecting films is provided.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Adaptable Ultraviolet Reflecting Polymeric Multilayer Coatings of High Refractive Index Contrast ; volume:3 ; number:11 ; year:2015 ; pages:1633-1639 ; extent:7
Advanced optical materials ; 3, Heft 11 (2015), 1633-1639 (gesamt 7)

Creator
Smirnov, José Raúl Castro
Ito, Masateru
Calvo, Mauricio Ernesto
López‐López, Carmen
Jiménez‐Solano, Alberto
Galisteo‐López, Juan Francisco
Zavala‐Rivera, Paul
Tanaka, Koichiro
Sivaniah, Easan
Míguez, Hernán

DOI
10.1002/adom.201500209
URN
urn:nbn:de:101:1-2022112707230489343055
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:31 AM CEST

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Associated

  • Smirnov, José Raúl Castro
  • Ito, Masateru
  • Calvo, Mauricio Ernesto
  • López‐López, Carmen
  • Jiménez‐Solano, Alberto
  • Galisteo‐López, Juan Francisco
  • Zavala‐Rivera, Paul
  • Tanaka, Koichiro
  • Sivaniah, Easan
  • Míguez, Hernán

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