N‐Heterocyclic Carbene Acyl Anion Organocatalysis by Ball‐Milling

to related objects

Abstract: The ability to conduct N‐heterocyclic carbene‐catalysed acyl anion chemistry under ball‐milling conditions is reported for the first time. This process has been exemplified through applications to intermolecular‐benzoin, intramolecular‐benzoin, intermolecular‐Stetter and intramolecular‐Stetter reactions including asymmetric examples and demonstrates that this mode of mechanistically complex organocatalytic reaction can operate under solvent‐minimised conditions.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: N‐Heterocyclic Carbene Acyl Anion Organocatalysis by Ball‐Milling ; volume:13 ; number:1 ; year:2020 ; pages:131-135 ; extent:5
ChemSusChem ; 13, Heft 1 (2020), 131-135 (gesamt 5)

Creator: Nicholson, William I.
Seastram, Alex C.
Iqbal, Saqib A.
Reed‐Berendt, Benjamin G.
Morrill, Louis C.
Browne, Duncan L.

DOI: 10.1002/cssc.201902346

URN: urn:nbn:de:101:1-2022060907393759350935

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:24 AM CEST

Data provider

This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.

Show original at data provider

Associated

Nicholson, William I.
Seastram, Alex C.
Iqbal, Saqib A.
Reed‐Berendt, Benjamin G.
Morrill, Louis C.
Browne, Duncan L.

Other Objects (12)

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?

Desymmetrization of N-Cbz glutarimides through N-heterocyclic carbene organocatalysis

The Mechanism of N‐Heterocyclic Carbene Organocatalysis through a Magnifying Glass

Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

Aufsatzsammlung

N-heterocyclic carbenes in organocatalysis

Hochschulschrift

Cooperative catalytic systems based on N-heterocyclic carbene (NHC) organocatalysis and transition metal catalysis

Light‐Promoted Organocatalysis with N‐Heterocyclic Carbenes

Hochschulschrift

Oxidative N-heterocyclic carbene catalysis

Oxidative N‐Heterocyclic Carbene Catalysis

Electroredox carbene organocatalysis with iodide as promoter

First example of organocatalysis by cathodic N-heterocyclic carbene generation and accumulation using a divided electrochemical flow cell

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?

Desymmetrization of N-Cbz glutarimides through N-heterocyclic carbene organocatalysis

The Mechanism of N‐Heterocyclic Carbene Organocatalysis through a Magnifying Glass

Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

Aufsatzsammlung

N-heterocyclic carbenes in organocatalysis

Hochschulschrift

Cooperative catalytic systems based on N-heterocyclic carbene (NHC) organocatalysis and transition metal catalysis

Light‐Promoted Organocatalysis with N‐Heterocyclic Carbenes

Hochschulschrift

Oxidative N-heterocyclic carbene catalysis

Oxidative N‐Heterocyclic Carbene Catalysis

Electroredox carbene organocatalysis with iodide as promoter

First example of organocatalysis by cathodic N-heterocyclic carbene generation and accumulation using a divided electrochemical flow cell

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?

Desymmetrization of N-Cbz glutarimides through N-heterocyclic carbene organocatalysis

The Mechanism of N‐Heterocyclic Carbene Organocatalysis through a Magnifying Glass

Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

Aufsatzsammlung

N-heterocyclic carbenes in organocatalysis

Hochschulschrift

Cooperative catalytic systems based on N-heterocyclic carbene (NHC) organocatalysis and transition metal catalysis

Light‐Promoted Organocatalysis with N‐Heterocyclic Carbenes

Hochschulschrift

Oxidative N-heterocyclic carbene catalysis

Oxidative N‐Heterocyclic Carbene Catalysis

Electroredox carbene organocatalysis with iodide as promoter

First example of organocatalysis by cathodic N-heterocyclic carbene generation and accumulation using a divided electrochemical flow cell

Cultural heritage institutions wishing to register will find more information here.

Fields marked * need to be filled in.

Username*

Please enter your username

Email*

Please enter your email address

Please do not fill this field

First name

Last name

Password*

Please enter your password

Confirm password*

Please enter the same password

I have read the terms of use and the privacy policy for the collection of personal data and accept them. *

This field is required.

I would like to subscribe to the newsletter of the Deutsche Digitale Bibliothek. See newsletter subscription info.

Account created

Your "My DDB" account has been successfully created. Before you can log in to your account, you must click the confirmation link in the message we just sent to the email address you provided.

N‐Heterocyclic Carbene Acyl Anion Organocatalysis by Ball‐Milling

Object Details

References and Relationships

Contributors, Places and Time

Further information

Data provider

Associated

Other Objects (12)

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?

Desymmetrization of N-Cbz glutarimides through N-heterocyclic carbene organocatalysis

The Mechanism of N‐Heterocyclic Carbene Organocatalysis through a Magnifying Glass

Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

N-heterocyclic carbenes in organocatalysis

Cooperative catalytic systems based on N-heterocyclic carbene (NHC) organocatalysis and transition metal catalysis

Light‐Promoted Organocatalysis with N‐Heterocyclic Carbenes

Oxidative N-heterocyclic carbene catalysis

Oxidative N‐Heterocyclic Carbene Catalysis

Electroredox carbene organocatalysis with iodide as promoter

First example of organocatalysis by cathodic N-heterocyclic carbene generation and accumulation using a divided electrochemical flow cell

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?

Desymmetrization of N-Cbz glutarimides through N-heterocyclic carbene organocatalysis

The Mechanism of N‐Heterocyclic Carbene Organocatalysis through a Magnifying Glass

Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

N-heterocyclic carbenes in organocatalysis

Cooperative catalytic systems based on N-heterocyclic carbene (NHC) organocatalysis and transition metal catalysis

Light‐Promoted Organocatalysis with N‐Heterocyclic Carbenes

Oxidative N-heterocyclic carbene catalysis

Oxidative N‐Heterocyclic Carbene Catalysis

Electroredox carbene organocatalysis with iodide as promoter

First example of organocatalysis by cathodic N-heterocyclic carbene generation and accumulation using a divided electrochemical flow cell

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?

Desymmetrization of N-Cbz glutarimides through N-heterocyclic carbene organocatalysis

The Mechanism of N‐Heterocyclic Carbene Organocatalysis through a Magnifying Glass

Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

N-heterocyclic carbenes in organocatalysis

Cooperative catalytic systems based on N-heterocyclic carbene (NHC) organocatalysis and transition metal catalysis

Light‐Promoted Organocatalysis with N‐Heterocyclic Carbenes

Oxidative N-heterocyclic carbene catalysis

Oxidative N‐Heterocyclic Carbene Catalysis

Electroredox carbene organocatalysis with iodide as promoter

First example of organocatalysis by cathodic N-heterocyclic carbene generation and accumulation using a divided electrochemical flow cell

Related objects

Reset password