Direct Laser Writing of Silica Nanoparticle Nanocomposites: Probing Mechanical Reinforcement and Understanding Structural Color from Design Parameters

Abstract: Nanocomposite materials have been thoroughly exploited in additive manufacturing, as a means to alter physical, chemical, and optical properties of resulting structures. Herein, nanocomposite materials suitable for direct laser writing (DLW) by two‐photon polymerization are presented. These materials, comprising silica nanoparticles, bring significant added value to the technology through physical reinforcement and controllable photonic properties. Incorporation into acrylate photoresists, via a one‐step fabrication process, enables the formation of complex structures with large overhangs. The inclusion of 150 nm silica nanoparticles in DLW photoresists at high concentrations, allows for the fabrication of composite microstructures that show reflected color, a product of the relative contributions from the quasi‐ordering and random scattering. Using common DLW design parameters, such as slicing distance and structure dimension, a wide gamut of structural color, in solution, using a set concentration of nanoparticles is demonstrated. Numerical modeling is employed to predict the reflected wavelength of the pixel arrays, across the visible spectrum, and this information is used to encode reflected colors into different pixel arrays.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Direct Laser Writing of Silica Nanoparticle Nanocomposites: Probing Mechanical Reinforcement and Understanding Structural Color from Design Parameters ; day:05 ; month:03 ; year:2024 ; extent:12
Small ; (05.03.2024) (gesamt 12)

Urheber
Augustine, Amrutha
Qian, Jing
Faraone, Teodora
Kolagatla, Srikanth
Prochukhan, Nadezda
Morris, Michael A.
Bradley, A. Louise
Florea, Larisa
Delaney, Colm

DOI
10.1002/smll.202310058
URN
urn:nbn:de:101:1-2024030514231418611973
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
14.08.2025, 10:45 MESZ

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Beteiligte

  • Augustine, Amrutha
  • Qian, Jing
  • Faraone, Teodora
  • Kolagatla, Srikanth
  • Prochukhan, Nadezda
  • Morris, Michael A.
  • Bradley, A. Louise
  • Florea, Larisa
  • Delaney, Colm

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