Selective O ‐Acylation of Enol Silyl Ethers with Acyl Fluorides Catalyzed by Fluoride Ions Derived from Potassium Fluoride and 18‐Crown‐6

Abstract: The fluoride ion‐catalyzed selective O‐acylation of enol silyl ethers with acyl fluorides using KF and 18‐Crown‐6 is described herein. This catalytic system facilitated the practical and facile reaction of a variety of enol silyl ethers derived from aromatic/aliphatic ketones and aldehydes with acyl fluorides to afford useful and valuable enol esters.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Selective O ‐Acylation of Enol Silyl Ethers with Acyl Fluorides Catalyzed by Fluoride Ions Derived from Potassium Fluoride and 18‐Crown‐6 ; day:29 ; month:01 ; year:2024 ; extent:6
ChemistryOpen ; (29.01.2024) (gesamt 6)

Creator
Sakai, Norio
Watanabe, Kota
Mori, Haruka
Maegawa, Yuki
Takeuchi, Ryuki
Ogiwara, Yohei
Ishida, Kento

DOI
10.1002/open.202300300
URN
urn:nbn:de:101:1-2024013014021263574797
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:29 AM CEST

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Associated

  • Sakai, Norio
  • Watanabe, Kota
  • Mori, Haruka
  • Maegawa, Yuki
  • Takeuchi, Ryuki
  • Ogiwara, Yohei
  • Ishida, Kento

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