Flow‐Integrated Preparation of Norbornadiene Precursors for Solar Thermal Energy Storage
Abstract: Molecular solar thermal (MOST) energy storage systems are getting increased attention related to renewable energy storage applications. Particularly, 2,3‐difunctionalized norbornadiene‐quadricyclane (NBD‐QC) switches bearing a nitrile (CN) group as one of the two substituents are investigated as promising MOST candidates thanks to their high energy storage densities and their red‐shifted absorbance. Moreover, such NBD systems can be prepared in large quantities (a requirement for MOST‐device applications) in flow through Diels‐Alder reaction between cyclopentadiene and appropriately functionalized propynenitriles. However, these acetylene precursors are traditionally prepared in batch from their corresponding acetophenones using reactive chemicals potentially leading to health and physical hazards, especially when working on a several‐grams scale. Here, we develop a multistep flow‐chemistry route to enhance the production of these crucial precursors. Furthermore, we assess the atom economy (AE) and the E‐factor showing improved green metrics compared to classical batch methods. Our results pave the way for a complete flow synthesis of NBDs with a positive impact on green chemistry aspects.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Flow‐Integrated Preparation of Norbornadiene Precursors for Solar Thermal Energy Storage ; day:09 ; month:01 ; year:2024 ; extent:8
ChemSusChem ; (09.01.2024) (gesamt 8)
- Urheber
-
Baggi, Nicolò
Hölzel, Helen
Schomaker, Hannes
Moreno, Kevin
Moth‐Poulsen, Kasper
- DOI
-
10.1002/cssc.202301184
- URN
-
urn:nbn:de:101:1-2024011014034271397995
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:36 MESZ
Datenpartner
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Baggi, Nicolò
- Hölzel, Helen
- Schomaker, Hannes
- Moreno, Kevin
- Moth‐Poulsen, Kasper
Ähnliche Objekte (12)
Push‐Pull Bis‐Norbornadienes for Solar Thermal Energy Storage
A Dual-Mode Hybrid System Combining Solar Thermal With Pumped Thermal Energy Storage
Precious metal-free molecular machines for solar thermal energy storage
Molecular solar thermal energy storage in photoswitch oligomers increases energy densities and storage times
ZnO-NaNO3 nanocomposites for solar thermal energy storage systems
Low Molecular Weight Norbornadiene Derivatives for Molecular Solar‐Thermal Energy Storage
Solar‐Thermal Energy Conversion and Storage Using Photoresponsive Azobenzene‐Containing Polymers
Synthetic mullite precursors : preparation, structure, and transformation behaviour
Synthetic mullite precursors : preparation, structure and transformation behaviour
Enhanced Thermal Performance of Nitrate Salts Composite with Compressed Expanded Graphite for Solar Thermal Energy Storage
Self-operation and low-carbon scheduling optimization of solar thermal power plants with thermal storage systems
Analysis of a solar dish–Stirling system with hybridization and thermal storage
Push‐Pull Bis‐Norbornadienes for Solar Thermal Energy Storage
A Dual-Mode Hybrid System Combining Solar Thermal With Pumped Thermal Energy Storage
Precious metal-free molecular machines for solar thermal energy storage
Molecular solar thermal energy storage in photoswitch oligomers increases energy densities and storage times
ZnO-NaNO3 nanocomposites for solar thermal energy storage systems
Low Molecular Weight Norbornadiene Derivatives for Molecular Solar‐Thermal Energy Storage
Solar‐Thermal Energy Conversion and Storage Using Photoresponsive Azobenzene‐Containing Polymers
Synthetic mullite precursors : preparation, structure, and transformation behaviour
Synthetic mullite precursors : preparation, structure and transformation behaviour
Enhanced Thermal Performance of Nitrate Salts Composite with Compressed Expanded Graphite for Solar Thermal Energy Storage
Self-operation and low-carbon scheduling optimization of solar thermal power plants with thermal storage systems
Analysis of a solar dish–Stirling system with hybridization and thermal storage
Push‐Pull Bis‐Norbornadienes for Solar Thermal Energy Storage
A Dual-Mode Hybrid System Combining Solar Thermal With Pumped Thermal Energy Storage
Precious metal-free molecular machines for solar thermal energy storage
Molecular solar thermal energy storage in photoswitch oligomers increases energy densities and storage times
ZnO-NaNO3 nanocomposites for solar thermal energy storage systems
Low Molecular Weight Norbornadiene Derivatives for Molecular Solar‐Thermal Energy Storage
Solar‐Thermal Energy Conversion and Storage Using Photoresponsive Azobenzene‐Containing Polymers
Synthetic mullite precursors : preparation, structure, and transformation behaviour
Synthetic mullite precursors : preparation, structure and transformation behaviour
Enhanced Thermal Performance of Nitrate Salts Composite with Compressed Expanded Graphite for Solar Thermal Energy Storage
Self-operation and low-carbon scheduling optimization of solar thermal power plants with thermal storage systems