Hydrogenation of Inorganic Metal Carbonates: A Review on Its Potential for Carbon Dioxide Utilization and Emission Reduction
Abstract: Carbonaceous minerals represent a valuable and abundant resource. Their exploitation is based on decarboxylation at elevated temperature and under oxidizing conditions, which inevitably release carbon dioxide into the atmosphere. Hydrogenation of inorganic metal carbonates opens up a new pathway for processing several metal carbonates. Preliminary experimental studies revealed significant advantages over conventional isolation technologies. Under a reducing hydrogen atmosphere, the temperature of decarboxylation is significantly lower. Carbon dioxide is not directly released into the atmosphere, but may be reduced to carbon monoxide, methane, and higher hydrocarbons, which adds value to the overall process. Apart from metal oxides in different oxidation states, metals in their elemental form may also be obtained if transition‐metal carbonates are processed under a hydrogen atmosphere. This review summarizes the most important findings and fields of the application of metal carbonate hydrogenation to elucidate the need for a detailed investigation into optimized process conditions for large‐scale applications.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Hydrogenation of Inorganic Metal Carbonates: A Review on Its Potential for Carbon Dioxide Utilization and Emission Reduction ; volume:11 ; number:19 ; year:2018 ; pages:3357-3375 ; extent:19
ChemSusChem ; 11, Heft 19 (2018), 3357-3375 (gesamt 19)
- Urheber
-
Lux, Susanne
Baldauf‐Sommerbauer, Georg
Siebenhofer, Matthäus
- DOI
-
10.1002/cssc.201801356
- URN
-
urn:nbn:de:101:1-2022090212205123732692
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
15.08.2025, 07:37 MESZ
Datenpartner
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Lux, Susanne
- Baldauf‐Sommerbauer, Georg
- Siebenhofer, Matthäus
Ähnliche Objekte (12)
Carbon dioxide utilization in propylene carbonate production process
Mechanochemical synthesis of amorphous inorganic carbonates
Catalytic Hydrogenation of Cyclic Carbonates using Manganese Complexes
Catalytic Hydrogenation of Cyclic Carbonates using Manganese Complexes
Transformation and utilization of carbon dioxide
Catalytic hydrogenation of carbon dioxide to methanol using molecular catalysts
Photocatalytic hydrogenation of acetophenone on a titanium dioxide cellulose film
Tailoring Inorganic Halide Perovskite Photocatalysts toward Carbon Dioxide Reduction
Synthesis of formic acid derivatives by catalytic hydrogenation of carbon dioxide
Catalytic hydrogenation of carbon dioxide and bicarbonates for benign hydrogen storage
Heterogeneous Catalytic Systems for Carbon Dioxide Hydrogenation to Value‐Added Chemicals
Efficient carbon dioxide hydrogenation to formic acid with buffering ionic liquids
Carbon dioxide utilization in propylene carbonate production process
Mechanochemical synthesis of amorphous inorganic carbonates
Catalytic Hydrogenation of Cyclic Carbonates using Manganese Complexes
Catalytic Hydrogenation of Cyclic Carbonates using Manganese Complexes
Transformation and utilization of carbon dioxide
Catalytic hydrogenation of carbon dioxide to methanol using molecular catalysts
Photocatalytic hydrogenation of acetophenone on a titanium dioxide cellulose film
Tailoring Inorganic Halide Perovskite Photocatalysts toward Carbon Dioxide Reduction
Synthesis of formic acid derivatives by catalytic hydrogenation of carbon dioxide
Catalytic hydrogenation of carbon dioxide and bicarbonates for benign hydrogen storage
Heterogeneous Catalytic Systems for Carbon Dioxide Hydrogenation to Value‐Added Chemicals
Efficient carbon dioxide hydrogenation to formic acid with buffering ionic liquids
Carbon dioxide utilization in propylene carbonate production process
Mechanochemical synthesis of amorphous inorganic carbonates
Catalytic Hydrogenation of Cyclic Carbonates using Manganese Complexes
Catalytic Hydrogenation of Cyclic Carbonates using Manganese Complexes
Transformation and utilization of carbon dioxide
Catalytic hydrogenation of carbon dioxide to methanol using molecular catalysts
Photocatalytic hydrogenation of acetophenone on a titanium dioxide cellulose film
Tailoring Inorganic Halide Perovskite Photocatalysts toward Carbon Dioxide Reduction
Synthesis of formic acid derivatives by catalytic hydrogenation of carbon dioxide
Catalytic hydrogenation of carbon dioxide and bicarbonates for benign hydrogen storage
Heterogeneous Catalytic Systems for Carbon Dioxide Hydrogenation to Value‐Added Chemicals