Ru Nanoparticles Supported on Mesoporous Al‐SBA‐15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol
Abstract: Furfuryl alcohol, which is the hydrogenated product of furfural, has been identified as a very promising platform chemical with high potential for applications in the manufacture of key chemicals, lubricants, fragrances, and pharmaceuticals. In this work, bare SB, and x % Ru/Al‐SB (x=1.5, 2.5, 3.5, and 4.5 wt. %) samples were fabricated by a hydrothermal method. Bare and most active catalysts were characterized by different techniques, such as BET, FE‐SEM, TEM, FT‐IR, and XRD, to understand their physical and chemical properties. An evaluation of the effects of various reaction parameters, such as catalyst loading, reaction temperature, and reaction time, on the catalytic performance, showed higher catalytic conversion of furfural and selectivity for the desired products. The most active RuS3 catalyst showed 100 % conversion of furfural and 99 % selectivity for furfuryl alcohol. It could be reused for five consecutive reaction cycles without significant loss of performance. In addition, Ru leaching and loss of conversion or selectivity were not noticed during the five‐run recycling test. The EDS elemental mapping analysis of the used catalyst established the preservation of the mesoporous structure, suggesting a strong interaction between the hexagonal porous silicate and the Ru nanoparticles.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Ru Nanoparticles Supported on Mesoporous Al‐SBA‐15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol ; volume:8 ; number:34 ; year:2023 ; extent:9
ChemistrySelect ; 8, Heft 34 (2023) (gesamt 9)
- Creator
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Kumaravel, Sakthivel
Durai, Mani
Kaliyamoorthy, Selvam
Kumaravel, Saranraj
Chandramoorthy, Chandrasatheesh
Avula, Balakrishna
Hasan, Imran
Kim, Myoung‐Jin
Balu, Krishnakumar
Ahn, Young‐Ho
- DOI
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10.1002/slct.202301787
- URN
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urn:nbn:de:101:1-2023090815174006007792
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:48 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Kumaravel, Sakthivel
- Durai, Mani
- Kaliyamoorthy, Selvam
- Kumaravel, Saranraj
- Chandramoorthy, Chandrasatheesh
- Avula, Balakrishna
- Hasan, Imran
- Kim, Myoung‐Jin
- Balu, Krishnakumar
- Ahn, Young‐Ho
Other Objects (12)
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Investigation on the Structure and Performance of Supported Ni Nanoparticles for the Hydrogenation of Furfural
Ethanol Steam Reforming for Hydrogen Production Over Hierarchical Macroporous Mesoporous SBA-15 Supported Nickel Nanoparticles
Impact of hydronium ions on the Pd-catalyzed furfural hydrogenation
Modification of SBA-15 for stabilizing supported oxides
Intensifying Cyclopentanone Synthesis from Furfural Using Supported Copper Catalysts
Investigation of the electrochemical furfural hydrogenation from mechanistic and electrosynthetic perspectives
In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines
Mesoporous carbon and microporous zeolite supported Ru catalysts for selective levulinic acid hydrogenation into γ-valerolactone
Nickel-Catalysed Vapour-Phase Hydrogenation of Furfural, Insights into Reactivity and Deactivation
Enhanced Performance of Laser‐Structured Copper Electrodes Towards Electrocatalytic Hydrogenation of Furfural
Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates
A Single-Atom Cobalt Catalyst Supported on SBA-15 for Hydrodeoxygenation and Hydrogenation
Investigation on the Structure and Performance of Supported Ni Nanoparticles for the Hydrogenation of Furfural
Ethanol Steam Reforming for Hydrogen Production Over Hierarchical Macroporous Mesoporous SBA-15 Supported Nickel Nanoparticles
Impact of hydronium ions on the Pd-catalyzed furfural hydrogenation
Modification of SBA-15 for stabilizing supported oxides
Intensifying Cyclopentanone Synthesis from Furfural Using Supported Copper Catalysts
Investigation of the electrochemical furfural hydrogenation from mechanistic and electrosynthetic perspectives
In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines
Mesoporous carbon and microporous zeolite supported Ru catalysts for selective levulinic acid hydrogenation into γ-valerolactone
Nickel-Catalysed Vapour-Phase Hydrogenation of Furfural, Insights into Reactivity and Deactivation
Enhanced Performance of Laser‐Structured Copper Electrodes Towards Electrocatalytic Hydrogenation of Furfural
Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates
A Single-Atom Cobalt Catalyst Supported on SBA-15 for Hydrodeoxygenation and Hydrogenation
Investigation on the Structure and Performance of Supported Ni Nanoparticles for the Hydrogenation of Furfural
Ethanol Steam Reforming for Hydrogen Production Over Hierarchical Macroporous Mesoporous SBA-15 Supported Nickel Nanoparticles
Impact of hydronium ions on the Pd-catalyzed furfural hydrogenation
Modification of SBA-15 for stabilizing supported oxides
Intensifying Cyclopentanone Synthesis from Furfural Using Supported Copper Catalysts
Investigation of the electrochemical furfural hydrogenation from mechanistic and electrosynthetic perspectives
In situ supported rhodium catalyst on mesoporous silica for chemoselective hydrogenation of nitriles to primary amines
Mesoporous carbon and microporous zeolite supported Ru catalysts for selective levulinic acid hydrogenation into γ-valerolactone
Nickel-Catalysed Vapour-Phase Hydrogenation of Furfural, Insights into Reactivity and Deactivation
Enhanced Performance of Laser‐Structured Copper Electrodes Towards Electrocatalytic Hydrogenation of Furfural