Catalytic Homologation‐Allylboration Sequence for Diastereo‐ and Enantioselective Synthesis of Densely Functionalized β‐Fluorohydrins with Tertiary Fluoride Stereocenters
Abstract: Homologation of trisubstituted fluoroalkenes followed by allylboration of aldehyde, ketone and imine substrates is suitable for synthesis of β‐fluorohydrin and amine products. In the presence of (R)‐iodo‐BINOL catalyst enantioselectivities up to 99 % can be achieved by formation of a single stereoisomer with adjacent stereocenters, of which one is a tertiary C−F center.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Catalytic Homologation‐Allylboration Sequence for Diastereo‐ and Enantioselective Synthesis of Densely Functionalized β‐Fluorohydrins with Tertiary Fluoride Stereocenters ; day:29 ; month:03 ; year:2023 ; extent:7
Angewandte Chemie / International edition. International edition ; (29.03.2023) (gesamt 7)
- Urheber
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Wang, Qiang
Eriksson, Lars
Szabó, Kálmán J.
- DOI
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10.1002/anie.202301481
- URN
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urn:nbn:de:101:1-2023032915250713630308
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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14.08.2025, 10:54 MESZ
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Beteiligte
- Wang, Qiang
- Eriksson, Lars
- Szabó, Kálmán J.
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