Volumetric Additive Manufacturing of Dicyclopentadiene by Solid‐State Photopolymerization

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Abstract: Polymerization in the solid state is generally infeasible due to restrictions on mobility. However, in this work, the solid‐state photopolymerization of crystalline dicyclopentadiene is demonstrated via photoinitiated ring‐opening metathesis polymerization. The source of mobility in the solid state is attributed to the plastic crystal nature of dicyclopentadiene, which yields local short‐range mobility due to orientational degrees of freedom. Polymerization in the solid state enables photopatterning, volumetric additive manufacturing of free‐standing structures, and fabrication with embedded components. Solid‐state photopolymerization of dicyclopentadiene offers a new paradigm for advanced and freeform fabrication of high‐performance thermosets.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Volumetric Additive Manufacturing of Dicyclopentadiene by Solid‐State Photopolymerization ; day:05 ; month:07 ; year:2024 ; extent:8
Advanced science ; (05.07.2024) (gesamt 8)

Creator
Hausladen, Matthew M.
Baca, Esteban
Nogales, Kyle A.
Appelhans, Leah N.
Kaehr, Bryan
Hamel, Craig M.
Leguizamon, Samuel C.

DOI
10.1002/advs.202402385
URN
urn:nbn:de:101:1-2407081455492.652862360207
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 10:46 AM CEST

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Associated

  • Hausladen, Matthew M.
  • Baca, Esteban
  • Nogales, Kyle A.
  • Appelhans, Leah N.
  • Kaehr, Bryan
  • Hamel, Craig M.
  • Leguizamon, Samuel C.

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