Monomer Transport via Collision in Emulsion Polymerization
Abstract: One of the questions still remaining regarding emulsion polymerization is the issue of mass transfer versus reaction limitation since, by its nature, emulsion polymerization requires monomer transport across an aqueous phase. This question is brought into focus lately by the growing use of miniemulsion polymerization in which the monomer transport step is much less important. This paper will explore the possible rate of monomer transport via collision and ratio this to the maximum rate of polymerization using the Damkohler analysis formality. Results indicate that systems relying on monomer transport by collision will be almost universally monomer‐transport‐limited, thus exhibiting lower‐than‐expected rates of polymerizations.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Monomer Transport via Collision in Emulsion Polymerization ; day:15 ; month:10 ; year:2024 ; extent:5
Macromolecular reaction engineering ; (15.10.2024) (gesamt 5)
- Urheber
-
Schork, F. Joseph
- DOI
-
10.1002/mren.202400030
- URN
-
urn:nbn:de:101:1-2410161428287.764472225732
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 15.08.2025, 07:35 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Schork, F. Joseph
Ähnliche Objekte (12)
Design of Emulsion Polymerization Reactors for Monomer‐Transport Limited Emulsion Polymerization
Monomer Transport by Collisions in (Mini) Emulsion Polymerization, a Personal Perspective
On the Mechanism of Nucleation and Monomer Transport in Inverse Emulsion Polymerization
Uniform and highly charged microgels via emulsion polymerization
Catalytic Polymerization in Emulsion
RAFT Polymerization of a Biorenewable/Sustainable Monomer via a Green Process
Silica/polymer core–shell particles prepared via soap-free emulsion polymerization
Mechanistic insights into Polar Monomer insertion polymerization from Acrylamides
Self-assembly of block copolymers synthesized via RAFT emulsion and dispersion polymerization
Emulsion-based free-radical retrograde-precipitation polymerization
Silica/polyethylene nanocomposites from catalytic emulsion polymerization
Submicron Polyethylene Particles from Catalytic Emulsion Polymerization
Design of Emulsion Polymerization Reactors for Monomer‐Transport Limited Emulsion Polymerization
Monomer Transport by Collisions in (Mini) Emulsion Polymerization, a Personal Perspective
On the Mechanism of Nucleation and Monomer Transport in Inverse Emulsion Polymerization
Uniform and highly charged microgels via emulsion polymerization
Catalytic Polymerization in Emulsion
RAFT Polymerization of a Biorenewable/Sustainable Monomer via a Green Process
Silica/polymer core–shell particles prepared via soap-free emulsion polymerization
Mechanistic insights into Polar Monomer insertion polymerization from Acrylamides
Self-assembly of block copolymers synthesized via RAFT emulsion and dispersion polymerization
Emulsion-based free-radical retrograde-precipitation polymerization
Silica/polyethylene nanocomposites from catalytic emulsion polymerization
Submicron Polyethylene Particles from Catalytic Emulsion Polymerization
Design of Emulsion Polymerization Reactors for Monomer‐Transport Limited Emulsion Polymerization
Monomer Transport by Collisions in (Mini) Emulsion Polymerization, a Personal Perspective
On the Mechanism of Nucleation and Monomer Transport in Inverse Emulsion Polymerization
Uniform and highly charged microgels via emulsion polymerization
Catalytic Polymerization in Emulsion
RAFT Polymerization of a Biorenewable/Sustainable Monomer via a Green Process
Silica/polymer core–shell particles prepared via soap-free emulsion polymerization
Mechanistic insights into Polar Monomer insertion polymerization from Acrylamides
Self-assembly of block copolymers synthesized via RAFT emulsion and dispersion polymerization
Emulsion-based free-radical retrograde-precipitation polymerization
Silica/polyethylene nanocomposites from catalytic emulsion polymerization