Synthesis of Long‐Chain Polyamides via Main‐Chain Modification of Polyethyleneketones
Abstract: Long‐chain polyamides (polyethyleneamides) were prepared from polyethylenes bearing in‐chain carbonyl groups (polyethyleneketones) by the oxime formation and successive Beckmann rearrangement. (Diethylamino) sulfur trifluoride (DAST) was utilized as a promoter, which allowed mild conversion of the oxime group in spite of low solubility of the polymers. The polyethyleneamide exhibited different tensile property compared to a commercial HDPE.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Synthesis of Long‐Chain Polyamides via Main‐Chain Modification of Polyethyleneketones ; volume:136 ; number:43 ; year:2024 ; extent:6
Angewandte Chemie ; 136, Heft 43 (2024) (gesamt 6)
- Urheber
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Lu, Yipu
Takahashi, Kohei
Zhou, Jian
Nontarin, Roopsung
Nakagawa, Shintaro
Yoshie, Naoko
Nozaki, Kyoko
- DOI
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10.1002/ange.202410849
- URN
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urn:nbn:de:101:1-2410141424487.965948222799
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:39 MESZ
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Beteiligte
- Lu, Yipu
- Takahashi, Kohei
- Zhou, Jian
- Nontarin, Roopsung
- Nakagawa, Shintaro
- Yoshie, Naoko
- Nozaki, Kyoko
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