Femtosecond nonadiabatic cascade and subsequent photofragmentation of XUV excited caffeine molecule
Abstract: We found that the XUV excited caffeine undergoes nondadabatic cascade via more than 100 shake-up states within the time constant of 40 fs by using femtosecond XUV-NIR pump-probe photo-ion spectroscopy and the SAC-CI level of ab-initio many-body theory. This nonadiabatic cascade results in the photofragmentation to specific large fragments. Furether ionization by NIR probe during the cascade increases the small fragments CH3+, CO+ etc. This results show that both vibronic coupling and electron correlation are the keys for the femtochemistry in the highly-correlated electronic excited states
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Anmerkungen
-
Journal of physics. Conference series. - 1412 (2020) , 142027, ISSN: 1742-6596
- Ereignis
-
Veröffentlichung
- (wo)
-
Freiburg
- (wer)
-
Universität
- (wann)
-
2021
- Urheber
-
Yamazaki, Kaoru
Marciniak, Alexandre
Maeda, Satoshi
Reduzzi, Maurizio
Despré, Victor
Hervé, Marius
Meziane, Mehdi
Niehaus, Thomas
Loriot, Vincent
Kuleff, Alexander I.
Schindler, Baptiste
Compagnon, Isabelle
Sansone, Giuseppe
Lepine, Franck
- DOI
-
10.1088/1742-6596/1412/14/142027
- URN
-
urn:nbn:de:bsz:25-freidok-1944120
- Rechteinformation
-
Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
25.03.2025, 13:52 MEZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Yamazaki, Kaoru
- Marciniak, Alexandre
- Maeda, Satoshi
- Reduzzi, Maurizio
- Despré, Victor
- Hervé, Marius
- Meziane, Mehdi
- Niehaus, Thomas
- Loriot, Vincent
- Kuleff, Alexander I.
- Schindler, Baptiste
- Compagnon, Isabelle
- Sansone, Giuseppe
- Lepine, Franck
- Universität
Entstanden
- 2021
Ähnliche Objekte (12)
Laser ablation driven by femtosecond optical and XUV pulses
Towards a compact thin-disk-based femtosecond XUV source
Towards a compact thin-disk-based femtosecond XUV source
Femtosecond XUV Photoelectron Spectroscopy of Organic Molecules in Aqueous Solution
Autoionization dynamics of helium nanodroplets resonantly excited by intense XUV laser pulses
Autoionization dynamics of He nanodroplets resonantly excited by intense XUV laser pulses
Autoionization dynamics of helium nanodroplets resonantly excited by intense XUV laser pulses
Femtosecond resolved diagnostics for electron beam and XUV seed temporal overlap at sFLASH
Multiple sequential ionization of valence n = 4 shell of krypton by intense femtosecond XUV pulses
Ultrafast spin dynamics of a ferrimagnet revealed by femtosecond soft X-ray and XUV radiation
Femtosecond dynamics of absorption and luminescence in optically excited semiconductors : theory and simulation
Investigation of the XUV emission from the interaction of intense femtosecond laser pulses with solid targets
Laser ablation driven by femtosecond optical and XUV pulses
Towards a compact thin-disk-based femtosecond XUV source
Towards a compact thin-disk-based femtosecond XUV source
Femtosecond XUV Photoelectron Spectroscopy of Organic Molecules in Aqueous Solution
Autoionization dynamics of helium nanodroplets resonantly excited by intense XUV laser pulses
Autoionization dynamics of He nanodroplets resonantly excited by intense XUV laser pulses
Autoionization dynamics of helium nanodroplets resonantly excited by intense XUV laser pulses
Femtosecond resolved diagnostics for electron beam and XUV seed temporal overlap at sFLASH
Multiple sequential ionization of valence n = 4 shell of krypton by intense femtosecond XUV pulses
Ultrafast spin dynamics of a ferrimagnet revealed by femtosecond soft X-ray and XUV radiation
Femtosecond dynamics of absorption and luminescence in optically excited semiconductors : theory and simulation
Investigation of the XUV emission from the interaction of intense femtosecond laser pulses with solid targets
Laser ablation driven by femtosecond optical and XUV pulses
Towards a compact thin-disk-based femtosecond XUV source
Towards a compact thin-disk-based femtosecond XUV source
Femtosecond XUV Photoelectron Spectroscopy of Organic Molecules in Aqueous Solution
Autoionization dynamics of helium nanodroplets resonantly excited by intense XUV laser pulses
Autoionization dynamics of He nanodroplets resonantly excited by intense XUV laser pulses
Autoionization dynamics of helium nanodroplets resonantly excited by intense XUV laser pulses
Femtosecond resolved diagnostics for electron beam and XUV seed temporal overlap at sFLASH
Multiple sequential ionization of valence n = 4 shell of krypton by intense femtosecond XUV pulses
Ultrafast spin dynamics of a ferrimagnet revealed by femtosecond soft X-ray and XUV radiation
Femtosecond dynamics of absorption and luminescence in optically excited semiconductors : theory and simulation