A Symmetrically π‐Expanded Carbazole Incorporating Fluoranthene Moieties
Abstract: A novel doubly cyclopentannulated carbazole which is accessible through a successive π‐expansion of di (1‐naphthylamine) is disclosed. The carbazole moiety is generated in the final step through intramolecular oxidative coupling. The π‐expansion of carbazole resulted in strongly altered optoelectronic and electrochemical properties. The solid‐state structure features an interesting packing motif with alternating face‐to‐face π⋅⋅⋅π and edge‐to‐face C−H⋅⋅⋅π interactions. The experimental findings were corroborated by theoretical calculations.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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A Symmetrically π‐Expanded Carbazole Incorporating Fluoranthene Moieties ; day:05 ; month:10 ; year:2022 ; extent:1
Chemistry - a European journal ; (05.10.2022) (gesamt 1)
- Creator
- DOI
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10.1002/chem.202201424
- URN
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urn:nbn:de:101:1-2022100615065738608883
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:31 AM CEST
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Associated
- Vogel, Alexander
- Schreyer, Till
- Bergner, John
- Rominger, Frank
- Oeser, Thomas
- Kivala, Milan
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