Multiferroic Microstructure Created from Invariant Line Constraint

Abstract: Ferroic materials enable a multitude of emerging applications, and optimum functional properties are achieved when ferromagnetic and ferroelectric properties are coupled to a first‐order ferroelastic transition. In bulk materials, this first‐order transition involves an invariant habit plane, connecting coexisting phases: austenite and martensite. Theory predicts that this plane should converge to a line in thin films, but experimental evidence is missing. Here, the martensitic and magnetic microstructure of a freestanding epitaxial magnetic shape memory film is analyzed. It is shown that the martensite microstructure is determined by an invariant line constraint using lattice parameters of both phases as the only input. This line constraint explains most of the observable features, which differ fundamentally from bulk and constrained films. Furthermore, this finite‐size effect creates a remarkable checkerboard magnetic domain pattern through multiferroic coupling. The findings highlight the decisive role of finite‐size effects in multiferroics.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Multiferroic Microstructure Created from Invariant Line Constraint ; day:25 ; month:10 ; year:2024 ; extent:11
Advanced functional materials ; (25.10.2024) (gesamt 11)

Creator
Kar, Satyakam
Ikeda, Yuki
Nielsch, Kornelius
Reith, Heiko
Maaß, Robert
Fähler, Sebastian

DOI
10.1002/adfm.202416638
URN
urn:nbn:de:101:1-2410251453178.872117353609
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.04.0025, 6:20 AM CET

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