Green and Rapid Hydrothermal Crystallization and Synthesis of Fully Conjugated Aromatic Compounds

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Abstract: Highly fused, fully conjugated aromatic compounds are interesting candidates for organic electronics. With higher crystallinity their electronic properties improve. It is shown here that the crystallization of three archetypes of such molecules—pentacenetetrone, indigo, and perinone—can be achieved hydrothermally. Given their molecular structure, this is a truly startling finding. In addition, it is demonstrated that perinone can also be synthesized in solely high‐temperature water from the starting compounds naphthalene bisanhydride and o‐phenylene diamine without the need for co‐solvents or catalysts. The transformation can be drastically accelerated by the application of microwave irradiation. This is the first report on the hydrothermal generation of two fused heterocycles.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Green and Rapid Hydrothermal Crystallization and Synthesis of Fully Conjugated Aromatic Compounds ; volume:57 ; number:38 ; year:2018 ; pages:12270-12274 ; extent:5
Angewandte Chemie / International edition. International edition ; 57, Heft 38 (2018), 12270-12274 (gesamt 5)

Creator: Taublaender, M. Josef
Glöcklhofer, Florian
Marchetti-Deschmann, Martina
Unterlass, Miriam M.

DOI: 10.1002/anie.201801277

URN: urn:nbn:de:101:1-2022090619485221963676

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:36 AM CEST

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