Probing the Hidden Photoisomerization of a Symmetric Phosphaalkene Switch
Abstract: In this study, we present the synthesis and analysis of a novel, air‐stable, and solvent‐resistant phosphaalkene switch. Using this symmetric switch, we have demonstrated degenerate photoisomerization experimentally for the first time. With a combination of photochemical‐exchange NMR spectroscopy, ultrafast transient absorption spectroscopy, and quantum chemical calculations, we elucidate the isomerization mechanism of this symmetric phosphaalkene, comparing it to two other known molecules belonging to this class. Our findings highlight the critical role of the isolobal analogy between C=P and C=C bonds in governing nanoscale molecular motion and break new ground for our understanding of light‐induced molecular processes in symmetric heteroalkene systems.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Probing the Hidden Photoisomerization of a Symmetric Phosphaalkene Switch ; day:13 ; month:12 ; year:2024 ; extent:8
Angewandte Chemie / International edition. International edition ; (13.12.2024) (gesamt 8)
- Creator
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Deka, Rajesh
Steen, Jorn D.
Hilbers, Michiel F.
Roeterdink, Wim G.
Iagatti, Alessandro
Xiong, Ruisheng
Buma, Wybren Jan
Di Donato, Mariangela
Orthaber, Andreas
Crespi, Stefano
- DOI
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10.1002/anie.202419943
- URN
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urn:nbn:de:101:1-2412141312048.617538318311
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:31 AM CEST
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Associated
- Deka, Rajesh
- Steen, Jorn D.
- Hilbers, Michiel F.
- Roeterdink, Wim G.
- Iagatti, Alessandro
- Xiong, Ruisheng
- Buma, Wybren Jan
- Di Donato, Mariangela
- Orthaber, Andreas
- Crespi, Stefano
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Probing the Hidden Photoisomerization of a Symmetric Phosphaalkene Switch
Probing octupolar hidden order via Janus impurities
Probing neutron-hidden neutron transitions with the MURMUR experiment
Probing hidden leptonic scalar portals using the NA64 experiment at CERN
Probing the thermodynamics of SU(N)-symmetric Fermi gases with ultracold atoms
Probing chiral-symmetric higher-order topological insulators with multipole winding number
A formula for hidden regular variation behavior for symmetric stable distributions
Probing the Higgs sector of the minimal Left-Right symmetric model at future hadron colliders
Probing SU(N)-symmetric orbital interactions with ytterbium Fermi gases in optical lattices
Probing regular MOG static spherically symmetric spacetime using greybody factors and quasinormal modes
The switch line
The Hidden Costs of Hidden Debt
Probing the Hidden Photoisomerization of a Symmetric Phosphaalkene Switch
Probing octupolar hidden order via Janus impurities
Probing neutron-hidden neutron transitions with the MURMUR experiment
Probing hidden leptonic scalar portals using the NA64 experiment at CERN
Probing the thermodynamics of SU(N)-symmetric Fermi gases with ultracold atoms
Probing chiral-symmetric higher-order topological insulators with multipole winding number
A formula for hidden regular variation behavior for symmetric stable distributions
Probing the Higgs sector of the minimal Left-Right symmetric model at future hadron colliders
Probing SU(N)-symmetric orbital interactions with ytterbium Fermi gases in optical lattices
Probing regular MOG static spherically symmetric spacetime using greybody factors and quasinormal modes
The switch line