On‐Surface Reactive Planarization of Pt (II) Complexes
Abstract: A series of Pt (II) complexes with tetradentate luminophores has been designed, synthesized, and deposited on coinage metal surfaces with the aim to produce highly planar self‐assembled monolayers. Low‐temperature scanning tunneling microscopy (STM) and density functional theory (DFT) calculations reveal a significant initial nonplanarity for all complexes. A subsequent metal‐catalyzed separation of the nonplanar moiety at the bridging unit via the scission of a C−N bond is observed, leaving behind a largely planar core complex. The activation barrier of this bond scission process is found to depend strongly on the chemical nature of both bridging group and coordination plane, and to increase from Cu (111) through Ag (111) to Au (111).
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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On‐Surface Reactive Planarization of Pt (II) Complexes ; volume:58 ; number:43 ; year:2019 ; pages:15396-15400 ; extent:5
Angewandte Chemie / International edition. International edition ; 58, Heft 43 (2019), 15396-15400 (gesamt 5)
- Urheber
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Ren, Jindong
Cnudde, Marvin
Brünink, Dana
Buss, Stefan
Daniliuc, Constantin Gabriel
Liu, Lacheng
Fuchs, Harald
Strassert, Cristian A.
Gao, Hong‐Ying
Doltsinis, Nikos L.
- DOI
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10.1002/anie.201906247
- URN
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urn:nbn:de:101:1-2022071211251148977412
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:36 MESZ
Datenpartner
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Beteiligte
- Ren, Jindong
- Cnudde, Marvin
- Brünink, Dana
- Buss, Stefan
- Daniliuc, Constantin Gabriel
- Liu, Lacheng
- Fuchs, Harald
- Strassert, Cristian A.
- Gao, Hong‐Ying
- Doltsinis, Nikos L.
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