Changing Liquid Crystal Helical Pitch with a Reversible Rotaxane Switch
Abstract: The transmission of chiral information between the molecular, meso and microscopic scales is a facet of biology that remains challenging to understand mechanistically and to mimic with artificial systems. Here we demonstrate that the dynamic change in the expression of the chirality of a rotaxane can be transduced into a change in pitch of a soft matter system. Shuttling the position of the macrocycle from far‐away‐from to close‐to a point‐chiral center on the rotaxane axle changes the expression of the chiral information that is transmitted across length scales; from nanometer scale constitutional chirality that affects the conformation of the macrocycle, to the centimeter scale chirality of the liquid crystal phase, significantly changing the pitch length of the chiral nematic structure.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Changing Liquid Crystal Helical Pitch with a Reversible Rotaxane Switch ; day:26 ; month:03 ; year:2024 ; extent:6
Angewandte Chemie ; (26.03.2024) (gesamt 6)
- Creator
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Chen, Sujun
Katsonis, Nathalie
Leigh, David A.
Patanapongpibul, Manee
Ryabchun, Alexander
Zhang, Liang
- DOI
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10.1002/ange.202401291
- URN
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urn:nbn:de:101:1-2024032613424944287889
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:55 AM CEST
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Associated
- Chen, Sujun
- Katsonis, Nathalie
- Leigh, David A.
- Patanapongpibul, Manee
- Ryabchun, Alexander
- Zhang, Liang
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Schätzung der Skalierungs- und Mimikparameter für ein 3D-Gesichtsmodell in der Bewegtbildcodierung
Bifurcation analysis and control of the valve-controlled hydraulic cylinder system
Anti-control of Hopf bifurcation for a chaotic system
Solutions to problems about potentially K s, t -bigraphic pair
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Changing Liquid Crystal Helical Pitch with a Reversible Rotaxane Switch
Schätzung der Skalierungs- und Mimikparameter für ein 3D-Gesichtsmodell in der Bewegtbildcodierung
Bifurcation analysis and control of the valve-controlled hydraulic cylinder system
Anti-control of Hopf bifurcation for a chaotic system
Solutions to problems about potentially K s, t -bigraphic pair
Poverty and health-related quality of life: a cross-sectional study in rural China
Inverse spectral problem of a class of fourth-order eigenparameter-dependent boundary value problems
Dominant role of charged meteoric smoke particles in the polar mesospheric clouds
A20 haploinsufficiency in a neonate caused by a large deletion on chromosome 6q
Responses of CIPS/AIM noctilucent clouds to the interplanetary magnetic field
Regulation of sulfur molecules for advanced lithium–sulfur batteries: strategies, mechanisms, and characterizations