Straightforward Access to Multifunctional π‐Conjugated P‐Heterocycles Featuring an Internal Ylidic Bond **
Abstract: We report the straightforward one‐pot synthesis of novel 5‐ or 6‐membered P‐heterocycles featuring an internal ylidic bond: P‐containing acenaphthylenes and phenanthrenes. The stability of the compounds tolerates post‐functionalization through direct arylation to introduce electron‐rich/poor substituents and the synthetic strategy is also compatible with the preparation of more elaborate polyaromatic scaffolds such as acenes and helicenes. Using a joint experimental (X‐ray analysis, optical and redox properties) and theoretical approach, we perform a full structure–property relationships study on these new platforms. In particular, we show that molecular engineering allows not only tuning their absorption/emission across the entire visible range but also endowing them with chiroptical or non‐linear optical properties, making them valuable dyes for a large panel of photonic or opto‐electronic applications.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Straightforward Access to Multifunctional π‐Conjugated P‐Heterocycles Featuring an Internal Ylidic Bond ** ; day:23 ; month:06 ; year:2022 ; extent:1
Angewandte Chemie / International edition. International edition ; (23.06.2022) (gesamt 1)
- Urheber
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Delouche, Thomas
Caytan, Elsa
Cordier, Marie
Roisnel, Thierry
Taupier, Grégory
Molard, Yann
Vanthuyne, Nicolas
Le Guennic, Boris
Hissler, Muriel
Jacquemin, Denis
Bouit, Pierre‐Antoine
- DOI
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10.1002/anie.202205548
- URN
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urn:nbn:de:101:1-2022062415163505234956
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:27 MESZ
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Beteiligte
- Delouche, Thomas
- Caytan, Elsa
- Cordier, Marie
- Roisnel, Thierry
- Taupier, Grégory
- Molard, Yann
- Vanthuyne, Nicolas
- Le Guennic, Boris
- Hissler, Muriel
- Jacquemin, Denis
- Bouit, Pierre‐Antoine
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