Alternating Terpolymers through Cyclopolymerization and Subsequent Orthogonal Functionalization
Abstract: A method for the synthesis of functionalized alternating copolymers by reversible deactivation radical polymerization was developed. Copolymerization by reversible addition–fragmentation chain transfer of hexenyl vinyl ether with a novel fluorinated divinyl monomer yields alternating cyclopolymers that can be chemoselectively modified by three distinct orthogonal functionalization reactions. Along the thiol‐ene click reaction and amidation, a third functionalization was achieved via NHC‐catalyzed transesterification or acylation resulting in a small library of ABC‐type alternating terpolymers.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Alternating Terpolymers through Cyclopolymerization and Subsequent Orthogonal Functionalization ; day:04 ; month:07 ; year:2022 ; extent:1
Angewandte Chemie / International edition. International edition ; (04.07.2022) (gesamt 1)
- Urheber
- DOI
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10.1002/anie.202206964
- URN
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urn:nbn:de:101:1-2022070515051408335810
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:22 MESZ
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Beteiligte
- Gerdt, Philipp
- Studer, Armido
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