Cross‐Dehydrogenative Coupling Polymerization via C−H Activation for the Synthesis of Conjugated Polymers

Abstract: Owing to their versatile (opto) electronic properties, conjugated polymers have found application in several organic electronic devices. Cross‐coupling reactions such as Stille, Suzuki, Kumada couplings, and direct arylation reactions have proved to be effective for their synthesis. More atom‐efficient oxidative direct arylation polymerization has also been reported for making homopolymers. However, growing interest toward donor‐acceptor polymers has led to the recent emergence of cross‐dehydrogenative coupling (CDC) polymerization to synthesize alternating copolymers without any prefunctionalization of monomers. Metal‐catalyzed cross‐coupling of two simple arenes via double C−H activation, or of an arene with an alkene via oxidative Heck‐type reaction have been used so far for CDC polymerization. In this article, we discuss the development of CDC polymerization protocols along with the relevant small molecule CDC reactions for an improved understanding of these reactions.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Cross‐Dehydrogenative Coupling Polymerization via C−H Activation for the Synthesis of Conjugated Polymers ; day:16 ; month:03 ; year:2023 ; extent:15
Angewandte Chemie / International edition. International edition ; (16.03.2023) (gesamt 15)

Creator
Chakraborty, Baitan
Luscombe, Christine

DOI
10.1002/anie.202301247
URN
urn:nbn:de:101:1-2023031614280652095473
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 10:51 AM CEST

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