Dynamic Bonds: Adaptable Timescales for Responsive Materials
Abstract: Dynamic bonds introduce unique properties such as self‐healing, recyclability, shape memory, and malleability to polymers. Significant efforts have been made to synthesize a variety of dynamic linkers, creating a diverse library of materials. In addition to the development of new dynamic chemistries, fine‐tuning of dynamic bonds has emerged as a technique to modulate dynamic properties. This Review highlights approaches for controlling the timescales of dynamic bonds in polymers. Particularly, eight dynamic bonds are considered, including urea/urethanes, boronic esters, Thiol–Michael exchange, Diels–Alder adducts, transesterification, imine bonds, coordination bonds, and hydrogen bonding. This Review emphasizes how structural modifications and external factors have been used as tools to tune the dynamic character of materials. Finally, this Review proposes strategies for tailoring the timescales of dynamic bonds in polymer materials through both kinetic effects and modulating bond thermodynamics.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Dynamic Bonds: Adaptable Timescales for Responsive Materials ; day:02 ; month:11 ; year:2022 ; extent:1
Angewandte Chemie / International edition. International edition ; (02.11.2022) (gesamt 1)
- Creator
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Wanasinghe, Shiwanka V.
Dodo, Obed J.
Konkolewicz, Dominik
- DOI
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10.1002/anie.202206938
- URN
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urn:nbn:de:101:1-2022110314020337903771
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:37 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Wanasinghe, Shiwanka V.
- Dodo, Obed J.
- Konkolewicz, Dominik
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