Modelling Development in Radical (Co) Polymerization of Multivinyl Monomers

Abstract: Radical polymerization (RP) of multivinyl monomers (MVMs) provides a facile solution for manipulating polymer topology and has received increasing attention due to their industrial and academic significance. Continuous efforts have been made to understand their mechanism, which is the key to regulating materials structure. Modelling techniques have become a powerful tool that can provide detailed information on polymerization kinetics which is inaccessible by experiments. Many publications have reported the combination of experiments and modelling for free radical polymerization (FRP) and reversible‐deactivation radical polymerizations (RDRP) of MVMs. Herein, a minireview is presented for the most important modelling techniques and their applications in FRP/RDRP of MVMs. This review hopes to illustrate that the combination of modelling and wet experiments can be a great asset to polymer researchers and inspire new thinking for the future MVMs experiment optimization and product design.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Modelling Development in Radical (Co) Polymerization of Multivinyl Monomers ; day:14 ; month:12 ; year:2022 ; extent:1
Angewandte Chemie / International edition. International edition ; (14.12.2022) (gesamt 1)

Creator
Lyu, Jing
Li, Yinghao
Li, Zishan
Polanowski, Piotr
Jeszka, Jeremiasz K.
Matyjaszewski, Krzysztof
Wang, Wenxin

DOI
10.1002/anie.202212235
URN
urn:nbn:de:101:1-2022121514153073692772
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:30 AM CEST

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Associated

  • Lyu, Jing
  • Li, Yinghao
  • Li, Zishan
  • Polanowski, Piotr
  • Jeszka, Jeremiasz K.
  • Matyjaszewski, Krzysztof
  • Wang, Wenxin

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