Stereo‐Structural Fine Tuning of Chromaticity

Abstract: Lanthanoid carboxylates were synthesized and in situ self‐assembled to illustrate temperature‐driven evolution in chromaticity. Evolution in structure (crystallinity), composition, luminosity, and chromaticity were investigated revealing the coupled role of divergence in order/structure (spatial organization), and composition in tuning observed color. Loss of crystallinity or increase in residual carbon leads to decrease in luminosity even with increase in hue. Comparing Ho and Er congeners shows that the density of accessible transition states relates to shifts in low and high wavelength components of color. This work demonstrates that, just as interface dipoles can lead to change in semiconductor band gap, structure and composition can analogously alter observed color.

Object Details

• Location: Deutsche Nationalbibliothek Frankfurt am Main
• Extent: Online-Ressource
• Language: Englisch

References and Relationships

• Bibliographic citation: Stereo‐Structural Fine Tuning of Chromaticity ; day:29 ; month:05 ; year:2024 ; extent:8 ; Angewandte Chemie / International edition. International edition ; (29.05.2024) (gesamt 8)

Contributors, Places and Time

• Creator: Pauls, Alana M. ; Jamadgni, Dhanush U. ; George, Gary ; Gitua, John N. ; Thuo, Martin

Further information

• DOI: 10.1002/anie.202318949
• URN: urn:nbn:de:101:1-2405291439490.208087923566
• Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Last update: 14.08.2025, 11:00 AM CEST