Hypervalent Halogen Compounds in Electrochemical Reactions: Advantages and Prospects
Abstract: The clean and facile electrochemical synthesis of hypervalent iodine reagents is a fast growing field. In the past 5 years, a diverse number of reaction types have been established, from fluorinations, oxidative cyclizations, C−N and C−H couplings and oxidations. Electrochemistry is beneficial in terms of sustainability as the requirement for chemical oxidants is eliminated. This contributes to cleaner processes with limited by‐product waste. Often, the purification of iodine (III) compounds is simple, since electrolysis is performed in the absence stoichiometric oxidants. Significant breakthroughs have been made recently, including the first asymmetric application, electrocatalytic applications, and even the synthesis of bromine (III) reagents using similar methodologies.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Hypervalent Halogen Compounds in Electrochemical Reactions: Advantages and Prospects ; day:04 ; month:07 ; year:2023 ; extent:15
Advanced synthesis & catalysis ; (04.07.2023) (gesamt 15)
- Urheber
- DOI
-
10.1002/adsc.202300412
- URN
-
urn:nbn:de:101:1-2023070515121112115865
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
14.08.2025, 11:03 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Winterson, Bethan
- Bhattacherjee, Dhananjay
- Wirth, Thomas
Ähnliche Objekte (12)
Hypervalent Bromine (III) Compounds: Synthesis, Applications, Prospects
Electrochemical Generation of Hypervalent Bromine(III) Compounds
Electrochemical Generation of Hypervalent Bromine(III) Compounds
Electrochemical Fluorination of Alkenes by Hypervalent λ3-Iodane Mediator
Computational Design of Bidentate Hypervalent Iodine Catalysts in Halogen Bond‐Mediated Organocatalysis
The Emissive and Electrochemical Properties of Hypervalent Pyridine-Dipyrrolide Bismuth Complexes
The Emissive and Electrochemical Properties of Hypervalent Pyridine‐Dipyrrolide Bismuth Complexes
Predicting bond dissociation energies of cyclic hypervalent halogen reagents using DFT calculations and graph attention network model
Massive parallel sequencing in forensics: advantages, issues, technicalities, and prospects
Hypervalent Iodine for α,α-Dihalogenation
Hypervalent iodine-mediated intramolecular alkene halocyclisation
Electrochemical CO 2 Reduction: Commercial Innovations and Prospects
Hypervalent Bromine (III) Compounds: Synthesis, Applications, Prospects
Electrochemical Generation of Hypervalent Bromine(III) Compounds
Electrochemical Generation of Hypervalent Bromine(III) Compounds
Electrochemical Fluorination of Alkenes by Hypervalent λ3-Iodane Mediator
Computational Design of Bidentate Hypervalent Iodine Catalysts in Halogen Bond‐Mediated Organocatalysis
The Emissive and Electrochemical Properties of Hypervalent Pyridine-Dipyrrolide Bismuth Complexes
The Emissive and Electrochemical Properties of Hypervalent Pyridine‐Dipyrrolide Bismuth Complexes
Predicting bond dissociation energies of cyclic hypervalent halogen reagents using DFT calculations and graph attention network model
Massive parallel sequencing in forensics: advantages, issues, technicalities, and prospects
Hypervalent Iodine for α,α-Dihalogenation
Hypervalent iodine-mediated intramolecular alkene halocyclisation
Electrochemical CO 2 Reduction: Commercial Innovations and Prospects
Hypervalent Bromine (III) Compounds: Synthesis, Applications, Prospects
Electrochemical Generation of Hypervalent Bromine(III) Compounds
Electrochemical Generation of Hypervalent Bromine(III) Compounds
Electrochemical Fluorination of Alkenes by Hypervalent λ3-Iodane Mediator
Computational Design of Bidentate Hypervalent Iodine Catalysts in Halogen Bond‐Mediated Organocatalysis
The Emissive and Electrochemical Properties of Hypervalent Pyridine-Dipyrrolide Bismuth Complexes
The Emissive and Electrochemical Properties of Hypervalent Pyridine‐Dipyrrolide Bismuth Complexes
Predicting bond dissociation energies of cyclic hypervalent halogen reagents using DFT calculations and graph attention network model
Massive parallel sequencing in forensics: advantages, issues, technicalities, and prospects
Hypervalent Iodine for α,α-Dihalogenation
Hypervalent iodine-mediated intramolecular alkene halocyclisation