Polarized Emission in Chiral Quasi‐2D Perovskite Light‐Emitting Diode
Abstract: Chiral 2D perovskites synthesized using (R‐+)‐α‐Methylbenzylamine (R‐MBA) and (S–)‐α‐Methylbenzylamine (S‐MBA) as barrier molecules exhibit chirality at low n values, as confirmed by circular dichroism (CD) analysis. The Anisotropy factor decreases significantly with increasing the n value, reaching 0.0032 for pure 2D perovskite. These synthesized quasi‐2D chiral perovskites have been successfully integrated into light‐emitting diodes (LEDs), demonstrating polarized emission for the first time. Remarkably, n = 3, R enantiomer achieves a total external quantum efficiency (EQE) of 12.1%, with polarized EQE of 4%. In the case of n = 2, the total EQE for both enantiomers is 4.3%, with polarized EQE of 3.4%, higher than the non‐polarized EQE of 0.9%. Degree of Polarization (DOP) is employed to characterize the fraction of an electromagnetic wave that exhibits polarization. The DOP analysis reveals a significant increase for low dimensional perovskite. Particularly for n = 2, R enantiomer exhibits a DOP of 53% compared to 2.5% for the non‐chiral molecule BzA. These findings demonstrate efficient polarized emission in 2D chiral perovskite LEDs, indicating promising avenues for advanced optical device applications.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Polarized Emission in Chiral Quasi‐2D Perovskite Light‐Emitting Diode ; day:26 ; month:08 ; year:2024 ; extent:9
Advanced optical materials ; (26.08.2024) (gesamt 9)
- Urheber
- DOI
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10.1002/adom.202401205
- URN
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urn:nbn:de:101:1-2408261414588.991240746669
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:38 MESZ
Datenpartner
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Shpatz Dayan, Adva
- Schneider, Avi
- Azulay, Doron
- Paltiel, Yossi
- Etgar, Lioz