Fully Recyclable Cured Polymers for Sustainable 3D Printing

Abstract: The most prevalent materials used in the Additive Manufacturing era are polymers and plastics. Unfortunately, these materials are recognized for their negative environmental impact as they are primarily nonrecyclable, resulting in environmental pollution. In recent years, a new sustainable alternative to these materials has been emerging: Reversible Covalent Bond‐Containing Polymers (RCBPs). These materials can be recycled, reprocessed, and reused multiple times without losing their properties. Nonetheless, they have two significant drawbacks when used in 3D printing. First, some require adding new materials every reprinting cycle, and second, others require high temperatures for (re) printing, limiting recyclability, and increasing energy consumption. This study, thus, introduces fully recyclable RCBPs as a sustainable approach for radiation‐based printing technologies. This approach enables multiple (re) printing cycles at low temperatures (50 °C lower than the lowest reported) without adding new materials. It involves purposefully synthesized polymers that undergo reversible photopolymerization, composed of a tin‐based catalyst. An everyday microwave oven quickly depolymerized these polymers, obtaining complete reversibility.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Fully Recyclable Cured Polymers for Sustainable 3D Printing ; day:07 ; month:12 ; year:2023 ; extent:7
Advanced materials ; (07.12.2023) (gesamt 7)

Urheber
Jarach, Natanel
Dodiuk, Hanna
Kenig, Samuel
Magdassi, Shlomo

DOI
10.1002/adma.202307297
URN
urn:nbn:de:101:1-2023120814244573874930
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:36 MESZ

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Beteiligte

  • Jarach, Natanel
  • Dodiuk, Hanna
  • Kenig, Samuel
  • Magdassi, Shlomo

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