Coextrusion of Reaction‐Bonded Carbides by Robocasting

Coextrusion by robocasting is a suitable process for fabricating multimaterial ceramic structures. Herein, the robocasting process is used to fabricate core–shell structures, combined with subsequent liquid silicon infiltration (LSI). Thus, reaction‐bonded silicon carbide (RBSC), reaction‐bonded boron carbide (RBBC), and reaction‐bonded silicon–boron carbide composites are produced. The LSI process offers the possibility to circumvent high temperatures and pressures used in traditional fabrication. Pastes with high solid loading and necessary carbon content are used in order to combine the robocasting with the subsequent LSI process. The influence of the paste rheology on the sample fabrication of multimaterial core–shell structures of reaction‐bonded carbides is investigated. The key rheological data, such as the viscosities of the combined pastes, are correlated with the observations from the microstructural investigation using scanning electron microscopy. A correlation between the difference in viscosity and the core geometry can be established. Crack formation in the material combination of RBSC and RBBC is found and compared with layered multimaterial structures of reaction‐bonded carbides. Residual stresses, which can be used to explain the crack formation, are investigated using Raman spectroscopy.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Coextrusion of Reaction‐Bonded Carbides by Robocasting ; day:17 ; month:08 ; year:2023 ; extent:7
Advanced engineering materials ; (17.08.2023) (gesamt 7)

Creator
Gradaus, Marco
Wahl, Larissa
Cicconi, Maria Rita
Ligny, Dominique de
Travitzky, Nahum

DOI
10.1002/adem.202300729
URN
urn:nbn:de:101:1-2023081815224138153474
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 10:52 AM CEST

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