Crystallographic and structural characterization of heterometalic platinum complexes Part X. Heteropolynuclear pt complexes

Abstract: This review covers heteropolynuclear platinum complexes. There are over sixty examples with heterometal atoms as partners including non- transition metals, K, Cs, Mg, Ca, Sr, Tl, Sn, Pb, Zn, Cd, and transition metals: Cu, Ag, Fe, Co, Ni, Rh and Pd. In addition, there are examples for the lanthanides, Eu and Yb. The most common are Ag (x16) and K (x14). The predominant geometries for Pt (II) is square-planar and for Pt (IV) is octahedral. The overall structures are complex. In spite of the wide variety of heterometal atoms partners of platinum, there is “real” Pt-M bonds only with silver, ranging from 2.678 to 2.943 (I) Å (ave 2.855 Å). The mean Pt-Pt bond distance is 2.869 Å.

Object Details

• Location: Deutsche Nationalbibliothek Frankfurt am Main
• Extent: Online-Ressource
• Language: Englisch

References and Relationships

• Bibliographic citation: Crystallographic and structural characterization of heterometalic platinum complexes Part X. Heteropolynuclear pt complexes ; volume:13 ; number:1 ; year:2015 ; extent:21 ; Open chemistry ; 13, Heft 1 (2015) (gesamt 21)

Contributors, Places and Time

• Creator: Melník, Milan ; Mikuš, Peter ; Holloway, Clive E.

Further information

• DOI: 10.1515/chem-2015-0095
• URN: urn:nbn:de:101:1-2410151807459.694607388200
• Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Last update: 15.08.2025, 7:24 AM CEST