Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin

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Abstract: This report discloses the photochemical homolytic cleavage of iodine azide after its formation following release from polymer‐bound bisazido iodate (I) anions. A series of radical reactions are reported including the 1,2‐functionlization of alkenes and the unprecedented chemoselective oxidation of secondary alcohols in the presence of primary alcohols.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin ; volume:59 ; number:30 ; year:2020 ; pages:12376-12380 ; extent:5
Angewandte Chemie / International edition. International edition ; 59, Heft 30 (2020), 12376-12380 (gesamt 5)

Creator: Kösel, Teresa
Schulz, Göran
Dräger, Gerald
Kirschning, Andreas

DOI: 10.1002/anie.202003079

URN: urn:nbn:de:101:1-2022062006363127125997

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:37 AM CEST

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Kösel, Teresa
Schulz, Göran
Dräger, Gerald
Kirschning, Andreas

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Automated Crystal Structure Determination Has its Pitfalls: Correction to the Crystal Structures of Iodine Azide

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Oxidative azidations of phenols and ketones using iodine azide after release from an ion exchange resin

Controlling hazardous chemicals in microreactors: Synthesis with iodine azide

Aldehydes as powerful initiators for photochemical transformations

Photochemical cobalt hydride catalysis for newly selective transformations

A Stable and Safe Form of Iodine Azide: Polymer-Bound Bisazidoiodate(I)

Automated Crystal Structure Determination Has its Pitfalls: Correction to the Crystal Structures of Iodine Azide

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p-Toluenesulfonyl Azide

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Photochemical Transformations with Iodine Azide after Release from an Ion‐Exchange Resin

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Other Objects (12)

Photochemical Transformations with Iodine Azide after Release from an Ion-Exchange Resin

Oxidative azidations of phenols and ketones using iodine azide after release from an ion exchange resin

Controlling hazardous chemicals in microreactors: Synthesis with iodine azide

Aldehydes as powerful initiators for photochemical transformations

Photochemical cobalt hydride catalysis for newly selective transformations

A Stable and Safe Form of Iodine Azide: Polymer-Bound Bisazidoiodate(I)

A Stable and Safe Form of Iodine Azide: Polymer-Bound Bisazidoiodate(I)

Automated Crystal Structure Determination Has its Pitfalls: Correction to the Crystal Structures of Iodine Azide

Electrochemical and photochemical functionalization of Au and Si surfaces by grafting of diazonium and azide compounds

Synthetic Transformations Based on Homolysis of Iodine and Bismuth Complexes

p-Toluenesulfonyl Azide

The Azide‐Wittig Reaction

Photochemical Transformations with Iodine Azide after Release from an Ion-Exchange Resin

Oxidative azidations of phenols and ketones using iodine azide after release from an ion exchange resin

Controlling hazardous chemicals in microreactors: Synthesis with iodine azide

Aldehydes as powerful initiators for photochemical transformations

Photochemical cobalt hydride catalysis for newly selective transformations

A Stable and Safe Form of Iodine Azide: Polymer-Bound Bisazidoiodate(I)

A Stable and Safe Form of Iodine Azide: Polymer-Bound Bisazidoiodate(I)

Automated Crystal Structure Determination Has its Pitfalls: Correction to the Crystal Structures of Iodine Azide

Electrochemical and photochemical functionalization of Au and Si surfaces by grafting of diazonium and azide compounds

Synthetic Transformations Based on Homolysis of Iodine and Bismuth Complexes

p-Toluenesulfonyl Azide

The Azide‐Wittig Reaction

Photochemical Transformations with Iodine Azide after Release from an Ion-Exchange Resin

Oxidative azidations of phenols and ketones using iodine azide after release from an ion exchange resin

Controlling hazardous chemicals in microreactors: Synthesis with iodine azide

Aldehydes as powerful initiators for photochemical transformations

Photochemical cobalt hydride catalysis for newly selective transformations

A Stable and Safe Form of Iodine Azide: Polymer-Bound Bisazidoiodate(I)

A Stable and Safe Form of Iodine Azide: Polymer-Bound Bisazidoiodate(I)

Automated Crystal Structure Determination Has its Pitfalls: Correction to the Crystal Structures of Iodine Azide

Electrochemical and photochemical functionalization of Au and Si surfaces by grafting of diazonium and azide compounds

Synthetic Transformations Based on Homolysis of Iodine and Bismuth Complexes

p-Toluenesulfonyl Azide

The Azide‐Wittig Reaction

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