Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers

Abstract: The products of the SuFEx reaction between sulfonimidoyl fluorides and phenols, sulfonimidates, are shown to display dynamic covalent chemistry with other phenols. This reaction was shown to be enantiospecific, finished in minutes at room temperature in high yields, and useful for both asymmetric synthesis and sustainable polymer production. Its wide scope further extends the usefulness of SuFEx and related click chemistries.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers ; day:29 ; month:07 ; year:2022 ; extent:1
Angewandte Chemie ; (29.07.2022) (gesamt 1)

Creator
Chao, Yang
Krishna, Akash
Subramaniam, Muthusamy
Liang, Dong‐Dong
Pujari, Sidharam P.
Sue, Andrew C.‐H.
Li, Guanna
Miloserdov, Fedor M.
Zuilhof, Han

DOI
10.1002/ange.202207456
URN
urn:nbn:de:101:1-2022072915250183479212
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:22 AM CEST

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Associated

  • Chao, Yang
  • Krishna, Akash
  • Subramaniam, Muthusamy
  • Liang, Dong‐Dong
  • Pujari, Sidharam P.
  • Sue, Andrew C.‐H.
  • Li, Guanna
  • Miloserdov, Fedor M.
  • Zuilhof, Han

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