Rapid and Complete Surface Modification with Strain‐Promoted Oxidation‐Controlled Cyclooctyne‐1,2‐Quinone Cycloaddition (SPOCQ)
Abstract: Strain‐promoted oxidation‐controlled cyclooctyne‐1,2‐quinone cycloaddition (SPOCQ) between functionalized bicyclo[6.1.0]non‐4‐yne (BCN) and surface‐bound quinones revealed an unprecedented 100 % conjugation efficiency. In addition, monitoring by direct analysis in real time mass spectrometry (DART‐MS) revealed the underlying kinetics and activation parameters of this immobilization process in dependence on its microenvironment.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Rapid and Complete Surface Modification with Strain‐Promoted Oxidation‐Controlled Cyclooctyne‐1,2‐Quinone Cycloaddition (SPOCQ) ; volume:56 ; number:12 ; year:2017 ; pages:3299-3303 ; extent:5
Angewandte Chemie / International edition. International edition ; 56, Heft 12 (2017), 3299-3303 (gesamt 5)
- Creator
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Sen, Rickdeb
Escorihuela, Jorge
van Delft, Floris
Zuilhof, Han
- DOI
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10.1002/anie.201612037
- URN
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urn:nbn:de:101:1-2022092106585600527906
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:23 AM CEST
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Associated
- Sen, Rickdeb
- Escorihuela, Jorge
- van Delft, Floris
- Zuilhof, Han
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