High‐Throughput Multiparametric Screening of Solution Processed Bulk Heterojunction Solar Cells

Abstract: One of the major bottlenecks in the development of organic photovoltaics is the time needed to evaluate each material system. This time ranges from weeks to months if different variables such as blend composition, thickness, annealing, and additives are to be explored. In this study, the use of lateral gradients is proposed in order to evaluate the photovoltaic potential of a material system up to 50 times faster. A platform that combines blade coating using controllable velocity profiles (thickness gradients) with multichannel dispensers (composition gradients) and controlled lateral annealing variations (nanostructure gradients) is introduced. These samples are then analyzed using photocurrent and Raman imaging in order to correlate one to one the device performance, thickness, composition, and annealing temperature. The strength of the developed technology is shown by optimizing three different systems, namely PCDTBT:PC70BM, PTB7‐Th:PC70BM, and PffBT4T‐2OD:PC70BM, obtaining efficiencies ≈5%, 8%, and 9.5%, respectively, using less than 10 mg of each polymer in the process.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
High‐Throughput Multiparametric Screening of Solution Processed Bulk Heterojunction Solar Cells ; volume:4 ; number:10 ; year:2018 ; extent:13
Advanced electronic materials ; 4, Heft 10 (2018) (gesamt 13)

Creator
Sánchez‐Díaz, Antonio
Rodríguez‐Martínez, Xabier
Córcoles‐Guija, Laura
Mora‐Martín, Germán
Campoy‐Quiles, Mariano

DOI
10.1002/aelm.201700477
URN
urn:nbn:de:101:1-2022090306083256958050
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:30 AM CEST

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Associated

  • Sánchez‐Díaz, Antonio
  • Rodríguez‐Martínez, Xabier
  • Córcoles‐Guija, Laura
  • Mora‐Martín, Germán
  • Campoy‐Quiles, Mariano

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