Photocatalytic Partial Oxidation of 5‐Hydroxymethylfurfural (HMF) to 2,5‐Diformylfuran (DFF) Over a Covalent Triazine Framework in Water
Abstract: Conversion of biomass into high value products via environmentally benign processes remains a challenging task for chemists. Photocatalytic partial oxidation of the biochemical 5‐hydroxymethylfurfural (HMF) to 2,5‐diformylfuran (DFF) has attracted much attention as DFF is known to be a pivotal precursor in the biochemical industry. Previously, this reaction has been catalyzed with transition metal based catalytic systems in organic solvents. Herein, we report the use of a covalent triazine framework (CTF) as a highly stable and porous organic photoactive polymer for the photocatalytic partial oxidation of HMF to DFF in water, using molecular oxygen as a green oxidant. The photocatalyst showed high efficiency in affording DFF as the target product with good reusability.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Photocatalytic Partial Oxidation of 5‐Hydroxymethylfurfural (HMF) to 2,5‐Diformylfuran (DFF) Over a Covalent Triazine Framework in Water ; volume:4 ; number:8 ; year:2020 ; pages:571-576 ; extent:6
ChemPhotoChem ; 4, Heft 8 (2020), 571-576 (gesamt 6)
- Creator
- DOI
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10.1002/cptc.202000070
- URN
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urn:nbn:de:101:1-2022070612024311039525
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:21 AM CEST
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Associated
- Ayed, Cyrine
- Huang, Wei
- Kizilsavas, Gönül
- Landfester, Katharina
- Zhang, Kai A. I.
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