Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia Borane
Abstract: Ammonia borane (AB), a liquid hydrogen storage material, has attracted increasing attention for hydrogen utilization because of its high hydrogen content. However, the slow kinetics of AB hydrolysis and the indefinite catalytic mechanism remain significant problems for its large‐scale practical application. Thus, the development of efficient AB hydrolysis catalysts and the determination of their catalytic mechanisms are significant and urgent. A summary of the preparation process and structural characteristics of various supported catalysts is presented in this paper, including graphite, metal‐organic frameworks (MOFs), metal oxides, carbon nitride (CN), molybdenum carbide (MoC), carbon nanotubes (CNTs), boron nitride (h‐BN), zeolites, carbon dots (CDs), and metal carbide and nitride (MXene). In addition, the relationship between the electronic structure and catalytic performance is discussed to ascertain the actual active sites in the catalytic process. The mechanism of AB hydrolysis catalysis is systematically discussed, and possible catalytic paths are summarized to provide theoretical considerations for the designing of efficient AB hydrolysis catalysts. Furthermore, three methods for stimulating AB from dehydrogenation by‐products and the design of possible hydrogen product‐regeneration systems are summarized. Finally, the remaining challenges and future research directions for the effective development of AB catalysts are discussed.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia Borane ; day:28 ; month:04 ; year:2023 ; extent:49
Advanced science ; (28.04.2023) (gesamt 49)
- Creator
-
Guan, Shuyan
Liu, Yanyan
Zhang, Huanhuan
Shen, Ruofan
Wen, Hao
Kang, Naixin
Zhou, Jingjing
Liu, Baozhong
Fan, Yanping
Jiang, Jianchun
Li, Baojun
- DOI
-
10.1002/advs.202300726
- URN
-
urn:nbn:de:101:1-2023042915130822840422
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
14.08.2025, 10:45 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Guan, Shuyan
- Liu, Yanyan
- Zhang, Huanhuan
- Shen, Ruofan
- Wen, Hao
- Kang, Naixin
- Zhou, Jingjing
- Liu, Baozhong
- Fan, Yanping
- Jiang, Jianchun
- Li, Baojun
Other Objects (12)
Polymer Film Supported Bimetallic Au–Ag Catalysts for Electrocatalytic Oxidation of Ammonia Borane in Alkaline Media
Graphene hydrogel supported palladium nanoparticles as an efficient and reusable heterogeneous catalysts in the transfer hydrogenation of nitroarenes using ammonia borane as a hydrogen source
Ammonia–Borane-Mediated Reduction of Nitroalkenes
Efficient Organocatalytic Dehydrogenation of Ammonia Borane
Heterogeneous dirhodium catalysts: from supported to self-supported systems
Nano-nickel catalytic dehydrogenation of ammonia borane
Atomic structure of graphene supported heterogeneous model catalysts
Monodisperse nickel nanoparticles supported on SiO2 as an effective catalyst for the hydrolysis of ammonia-borane
Multiple reaction pathway on alkaline earth imide supported catalysts for efficient ammonia synthesis
Additive Manufacturing of Heterogeneous Catalysts: Development of Binder Jetting Printing Strategies for Al2O3-Supported Catalysts
Practical H2 supply from ammonia borane enabled by amorphous iron domain
Supported liquid phase catalysts
Polymer Film Supported Bimetallic Au–Ag Catalysts for Electrocatalytic Oxidation of Ammonia Borane in Alkaline Media
Graphene hydrogel supported palladium nanoparticles as an efficient and reusable heterogeneous catalysts in the transfer hydrogenation of nitroarenes using ammonia borane as a hydrogen source
Ammonia–Borane-Mediated Reduction of Nitroalkenes
Efficient Organocatalytic Dehydrogenation of Ammonia Borane
Heterogeneous dirhodium catalysts: from supported to self-supported systems
Nano-nickel catalytic dehydrogenation of ammonia borane
Atomic structure of graphene supported heterogeneous model catalysts
Monodisperse nickel nanoparticles supported on SiO2 as an effective catalyst for the hydrolysis of ammonia-borane
Multiple reaction pathway on alkaline earth imide supported catalysts for efficient ammonia synthesis
Additive Manufacturing of Heterogeneous Catalysts: Development of Binder Jetting Printing Strategies for Al2O3-Supported Catalysts
Practical H2 supply from ammonia borane enabled by amorphous iron domain
Supported liquid phase catalysts
Polymer Film Supported Bimetallic Au–Ag Catalysts for Electrocatalytic Oxidation of Ammonia Borane in Alkaline Media
Graphene hydrogel supported palladium nanoparticles as an efficient and reusable heterogeneous catalysts in the transfer hydrogenation of nitroarenes using ammonia borane as a hydrogen source
Ammonia–Borane-Mediated Reduction of Nitroalkenes
Efficient Organocatalytic Dehydrogenation of Ammonia Borane
Heterogeneous dirhodium catalysts: from supported to self-supported systems
Nano-nickel catalytic dehydrogenation of ammonia borane
Atomic structure of graphene supported heterogeneous model catalysts
Monodisperse nickel nanoparticles supported on SiO2 as an effective catalyst for the hydrolysis of ammonia-borane
Multiple reaction pathway on alkaline earth imide supported catalysts for efficient ammonia synthesis
Additive Manufacturing of Heterogeneous Catalysts: Development of Binder Jetting Printing Strategies for Al2O3-Supported Catalysts
Practical H2 supply from ammonia borane enabled by amorphous iron domain