Synthesis and Characterization of bis (Tetrahydrofurfuryl) Ether

Abstract: Despite the availability of a large number of alkyl tetrahydrofurfuryl ethers that have a wide range of applications, pure bis (tetrahydrofurfuryl) ether (BTHFE) has not been previously synthesized. Here, we report the synthesis of BTHFE (consisting of the RR, SS, and meso stereoisomers) at greater than 99 % purity from tetrahydrofurfuryl alcohol, using (tetrahydrofuran‐2‐yl) methyl methanesulfonate as an intermediate. Additionally, we demonstrate that BTHFE can be used as a non‐volatile solvent in poly (3,4‐propylenedioxythiophene)‐based supercapacitors. Supercapacitor devices employing solutions of the ionic liquid 1‐ethyl‐3‐methyl‐imidizolium bis (trifluoromethylsulfonyl) imide in BTHFE display similar performances to those prepared by using the neat ionic liquid as an electrolyte, although solution‐based devices exhibit a somewhat higher resistance.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Synthesis and Characterization of bis (Tetrahydrofurfuryl) Ether ; volume:5 ; number:4 ; year:2016 ; pages:297-300 ; extent:4
ChemistryOpen ; 5, Heft 4 (2016), 297-300 (gesamt 4)

Creator
Stenger‐Smith, John D.
Baldwin, Lawrence
Chafin, Andrew
Goodman, Paul A.

DOI
10.1002/open.201600013
URN
urn:nbn:de:101:1-2022111707402462464906
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:34 AM CEST

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Associated

  • Stenger‐Smith, John D.
  • Baldwin, Lawrence
  • Chafin, Andrew
  • Goodman, Paul A.

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