Stepwise Stiffening Chromophore Strategy Realizes a Series of Ultralong Blue Room‐Temperature Phosphorescent Materials
Abstract: Ultralong room‐temperature phosphorescent (URTP) materials have attracted wide attention in anti‐counterfeiting, optoelectronic display, and bio‐imaging due to their special optical properties. However, room‐temperature blue phosphorescent materials are very scarce during applications because of the need to simultaneously populate and stabilize high‐energy excited states. In this work, a stepwise stiffening chromophore strategy is proposed to suppress non‐radiative jump by continuously reducing the internal spin of the chromophore, and successfully developing a series of blue phosphorescent materials. Phosphorescence lifetimes of more than 3 s are achieved, with the longest lifetime reaching 5.44 s and lasting more than 70 s in the naked eye. As far as is know, this is the best result that has been reported. By adjusting the chromophore conjugation, multicolor phosphorescences from cyan to green have been realized. In addition, these chromophores exhibit the same excellent optical properties in urea and polyvinyl alcohmance (PVA). Finally, these materials are successfully applied to luminescent displays.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Stepwise Stiffening Chromophore Strategy Realizes a Series of Ultralong Blue Room‐Temperature Phosphorescent Materials ; day:24 ; month:06 ; year:2024 ; extent:10
Advanced science ; (24.06.2024) (gesamt 10)
- Urheber
-
Guan, Zhihao
Tang, Zhaorun
Zeng, Jianwen
Zheng, Yuewei
Ding, Lin
Chen, Dongzhi
Li, Houbin
Liu, Xinghai
- DOI
-
10.1002/advs.202402632
- URN
-
urn:nbn:de:101:1-2406241412359.751646038207
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
-
14.08.2025, 10:48 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Guan, Zhihao
- Tang, Zhaorun
- Zeng, Jianwen
- Zheng, Yuewei
- Ding, Lin
- Chen, Dongzhi
- Li, Houbin
- Liu, Xinghai
Ähnliche Objekte (12)
Multiemitting Ultralong Phosphorescent Carbonized Polymer Dots via Synergistic Enhancement Structure Design
Nylons with Highly-Bright and Ultralong Organic Room-Temperature Phosphorescence
Enhancing the performance of pure organic room-temperature phosphorescent luminophores
Development of fluorinated benzils and bisbenzils as room-temperature phosphorescent molecules
Ultralong lifetime and efficient room temperature phosphorescent carbon dots through multi-confinement structure design
Urea-formaldehyde resin room temperature phosphorescent material with ultra-long afterglow and adjustable phosphorescence performance
Heavy‐Atom‐Free Room‐Temperature Phosphorescent Rylene Imide for High‐Performing Organic Photovoltaics
A dish-like molecular architecture for dynamic ultralong room-temperature phosphorescence through reversible guest accommodation
Efficient intersystem crossing and tunable ultralong organic room-temperature phosphorescence via doping polyvinylpyrrolidone with polyaromatic hydrocarbons
Tailored Fabrication of Carbon Dot Composites with Full‐Color Ultralong Room‐Temperature Phosphorescence for Multidimensional Encryption
Modulating Aryl Azide Photolysis: Synthesis of a Room‐Temperature Phosphorescent Carboline in Cucurbit (7) uril Host
Highly Efficient Persistent Room‐Temperature Phosphorescence from Heavy Atom‐Free Molecules Triggered by Hidden Long Phosphorescent Antenna
Multiemitting Ultralong Phosphorescent Carbonized Polymer Dots via Synergistic Enhancement Structure Design
Nylons with Highly-Bright and Ultralong Organic Room-Temperature Phosphorescence
Enhancing the performance of pure organic room-temperature phosphorescent luminophores
Development of fluorinated benzils and bisbenzils as room-temperature phosphorescent molecules
Ultralong lifetime and efficient room temperature phosphorescent carbon dots through multi-confinement structure design
Urea-formaldehyde resin room temperature phosphorescent material with ultra-long afterglow and adjustable phosphorescence performance
Heavy‐Atom‐Free Room‐Temperature Phosphorescent Rylene Imide for High‐Performing Organic Photovoltaics
A dish-like molecular architecture for dynamic ultralong room-temperature phosphorescence through reversible guest accommodation
Efficient intersystem crossing and tunable ultralong organic room-temperature phosphorescence via doping polyvinylpyrrolidone with polyaromatic hydrocarbons
Tailored Fabrication of Carbon Dot Composites with Full‐Color Ultralong Room‐Temperature Phosphorescence for Multidimensional Encryption
Modulating Aryl Azide Photolysis: Synthesis of a Room‐Temperature Phosphorescent Carboline in Cucurbit (7) uril Host
Highly Efficient Persistent Room‐Temperature Phosphorescence from Heavy Atom‐Free Molecules Triggered by Hidden Long Phosphorescent Antenna
Multiemitting Ultralong Phosphorescent Carbonized Polymer Dots via Synergistic Enhancement Structure Design
Nylons with Highly-Bright and Ultralong Organic Room-Temperature Phosphorescence
Enhancing the performance of pure organic room-temperature phosphorescent luminophores
Development of fluorinated benzils and bisbenzils as room-temperature phosphorescent molecules
Ultralong lifetime and efficient room temperature phosphorescent carbon dots through multi-confinement structure design
Urea-formaldehyde resin room temperature phosphorescent material with ultra-long afterglow and adjustable phosphorescence performance
Heavy‐Atom‐Free Room‐Temperature Phosphorescent Rylene Imide for High‐Performing Organic Photovoltaics
A dish-like molecular architecture for dynamic ultralong room-temperature phosphorescence through reversible guest accommodation
Efficient intersystem crossing and tunable ultralong organic room-temperature phosphorescence via doping polyvinylpyrrolidone with polyaromatic hydrocarbons
Tailored Fabrication of Carbon Dot Composites with Full‐Color Ultralong Room‐Temperature Phosphorescence for Multidimensional Encryption
Modulating Aryl Azide Photolysis: Synthesis of a Room‐Temperature Phosphorescent Carboline in Cucurbit (7) uril Host