Long‐Range Chirality Recognition of a Polar Molecule on Au (111)

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Abstract: Chiral molecular self‐assemblies were usually achieved using short‐range intermolecular interactions, such as hydrogen‐, metal–organic, and covalent bonding. However, unavoidable surface defects, such as step edges, surface reconstructions, or site dislocations may limit the applicability of short‐range chirality recognition. Long‐range chirality recognition on surfaces would be an appealing but challenging strategy for chiral reservation across surface defects at long distances. Now, long‐range chirality recognition is presented between neighboring 3‐bromo‐naphthalen‐2‐ol (BNOL) stripes on an inert Au (111) surface across the herringbone reconstruction as investigated by STM and DFT calculations. The key to achieving such recognition is the herringbone reconstruction‐induced local dipole accumulation at the edges of the BNOL stripes. The neighboring stripes are then forced to adopt the same chirality to create the opposite edged dipoles and neutralize the neighbored dipole moments.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Long‐Range Chirality Recognition of a Polar Molecule on Au (111) ; volume:132 ; number:1 ; year:2020 ; pages:188-192 ; extent:5
Angewandte Chemie ; 132, Heft 1 (2020), 188-192 (gesamt 5)

Creator: Kong, Huihui
Qian, Yinyue
Liu, Xinbang
Wan, Xinling
Amirjalayer, Saeed
Fuchs, Harald

DOI: 10.1002/ange.201909593

URN: urn:nbn:de:101:1-2022052510591052711111

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:38 AM CEST

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Associated

Kong, Huihui
Qian, Yinyue
Liu, Xinbang
Wan, Xinling
Amirjalayer, Saeed
Fuchs, Harald

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