Multi‐Catalytic Metal‐Based Homogeneous‐Heterogeneous Systems in Organic Chemistry

Abstract: The combination of metal‐based homogeneous and heterogeneous catalysts in the same reaction media is a powerful, yet relatively unexplored approach in organic chemistry. This strategy can address important limitations associated with purely homogeneous or heterogeneous catalysis such as the incompatibility of different catalytic species in solution, or the limited tunability of solid catalysts, respectively. Moreover, the facile reusability of the solid catalyst, contributes to increase the overall sustainability of the process. As a result, this semi‐heterogeneous multi‐catalytic approach has unlocked significant advances in organic chemistry, improving existing reactions and even enabling the discovery of novel transformations, exemplified by the formal alkane metathesis. This concept article aims to showcase the benefits of this strategy through the exploration of diverse relevant examples from the literature, hoping to spur research on new metal‐based homogeneous‐heterogeneous catalyst combinations that will result in reactivity challenging to achieve by conventional homogeneous or heterogeneous catalysis alone.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Multi‐Catalytic Metal‐Based Homogeneous‐Heterogeneous Systems in Organic Chemistry ; day:20 ; month:08 ; year:2024 ; extent:9
Chemistry - a European journal ; (20.08.2024) (gesamt 9)

Creator
Arango‐Daza, Juan Camilo
Rivero‐Crespo, Miguel A.

DOI
10.1002/chem.202400443
URN
urn:nbn:de:101:1-2408211421427.782160045500
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 10:49 AM CEST

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Associated

  • Arango‐Daza, Juan Camilo
  • Rivero‐Crespo, Miguel A.

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